Home
Class 12
CHEMISTRY
Let C(NaCl) and C(BaSO(4)) be the conduc...

Let `C_(NaCl) and C_(BaSO_(4))` be the conductances (in S) measured for saturated aqueous solutions of NaCl and BaSO4, respectively, at a temperature T.
Which of the following is false?

A

`C_(NaCl)(T_(2))gtC_(NaCl)(T_(1))" for "T_(2) gt T_(1)`

B

`C_(BaSO_(4))(T_(2))gtC_(BaSO_(4))(T_(1))" for "T_(2) gt T_(1))`

C

Ionic mobilities of ions form both salts increase with T.

D

`C_(NaCl)gt gt C_(BaSO_(4))` at a given T

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the conductance of the two salts, NaCl and BaSO₄, at different temperatures and determine which statement is false among the given options. ### Step-by-Step Solution: 1. **Understanding Conductance**: Conductance (C) of an electrolyte solution is influenced by the concentration of ions and their mobility. Higher mobility and concentration lead to higher conductance. 2. **Analyzing NaCl**: - NaCl is a strong electrolyte that completely dissociates into Na⁺ and Cl⁻ ions in solution. - As temperature increases (from T1 to T2), the mobility of ions increases due to decreased intermolecular forces. This results in increased conductance. - Therefore, the statement that "conductance of NaCl at T2 is more than at T1" is **true**. 3. **Analyzing BaSO₄**: - BaSO₄ is a sparingly soluble salt, meaning it does not completely dissociate in water. Its solubility increases with temperature. - As temperature increases, more Ba²⁺ and SO₄²⁻ ions will dissolve, increasing the number of ions in solution and thus increasing conductance. - Therefore, the statement that "conductance of BaSO₄ at T2 is more than at T1" is also **true**. 4. **Ionic Mobility**: - The mobility of ions increases with temperature due to reduced forces of attraction between them. This is a general property of ionic solutions. - Thus, the statement "ionic mobility increases with temperature" is **true**. 5. **Comparing Conductance of NaCl and BaSO₄**: - NaCl, being highly soluble, will produce a larger number of ions compared to the limited dissociation of BaSO₄. - Therefore, the statement "the conductance of sodium chloride is very high compared to barium sulfate" is **true**. 6. **Conclusion**: - All the statements analyzed are true based on the properties of the salts and the effects of temperature on their conductance. ### Final Answer: None of the statements are false; all provided statements are true.

To solve the problem, we need to analyze the conductance of the two salts, NaCl and BaSO₄, at different temperatures and determine which statement is false among the given options. ### Step-by-Step Solution: 1. **Understanding Conductance**: Conductance (C) of an electrolyte solution is influenced by the concentration of ions and their mobility. Higher mobility and concentration lead to higher conductance. 2. **Analyzing NaCl**: ...
Promotional Banner

Topper's Solved these Questions

  • JEE MAINS 2020

    JEE MAINS PREVIOUS YEAR|Exercise CHEMSITRY|25 Videos
  • JEE MAINS

    JEE MAINS PREVIOUS YEAR|Exercise QUESTION|1 Videos
  • JEE MAINS 2021

    JEE MAINS PREVIOUS YEAR|Exercise Chemistry (Section B )|10 Videos

Similar Questions

Explore conceptually related problems

conductance of NaCl and BaSo_4 is C_1 AND C_2 at temperature T, then which of the following statement is correct

pH of an aqueous solution of NaCl at 85^@C should be

The lowering of vapour pressure of 0.1 M aqueous solution NaCl, CuSO_(4) and K_(2)SO_(4) are :

The lowering of vapour pressure of 0.1 M aqueous solution NaCl, CuSO_(4) and K_(2)SO_(4) are :

pH of an aqueous NaCl solution at 50^(@) C should be :

Which of the following gases are evolved by the electrolysis of aqueous solution of NaCl ?

BaSO_(4) is ionic and PCl_(3) is covalent but a saturated solution of BaSO_(4) is a weak electroyte, While that of PCl_(3) is a strong electrolyte. Explain?

4 L of 0.02 M aqueous solution of NaCl was diluted by adding 1 L of water. The molality of the resultant solution is……..

The pH of 1.0 aqueous solution of NaCL,CH_(3)COONa" and "NH_(4)Cl will follow the order :

JEE MAINS PREVIOUS YEAR-JEE MAINS 2020-CHEMSITRY
  1. Let C(NaCl) and C(BaSO(4)) be the conductances (in S) measured for sat...

    Text Solution

    |

  2. The correct statement with respect to dinitrogen is :

    Text Solution

    |

  3. Consider the following reactions :

    Text Solution

    |

  4. The major product obtained from the following reaction is :

    Text Solution

    |

  5. A solution of two components containing n1 moles of 1^(st) component a...

    Text Solution

    |

  6. The INCORRECT statement is :

    Text Solution

    |

  7. Consider the Assertion and Reason given below. Assertion (A) : Ethe...

    Text Solution

    |

  8. Arrange the following solutions in the decreasing order of pOH : (A...

    Text Solution

    |

  9. Among the sulphates of alkaline earth metals the solubilities of BeSO4...

    Text Solution

    |

  10. The major products of the following reaction are : CH3 -overset(CH...

    Text Solution

    |

  11. The major product of the following reaction is :

    Text Solution

    |

  12. The presence of soluble fluoride ion upto 1 ppm concentration in drink...

    Text Solution

    |

  13. The increasing order of pKb values of the following compounds is :

    Text Solution

    |

  14. Which of the following compounds shows geometrical isomerism ?

    Text Solution

    |

  15. The set that contains atomic numbers of only transition elements , is ...

    Text Solution

    |

  16. The variation of equilibrium constant with temperature is given below ...

    Text Solution

    |

  17. Kraft temperature is the temperature :

    Text Solution

    |

  18. For the reaction Fe2N(s)+(3)/(2)H2(g)=2Fe(s)+NH3(g)

    Text Solution

    |

  19. The species that has a spin -only magnetic moment of 5.9 BM , is : (...

    Text Solution

    |

  20. The lanthanoid that does NOT show +4 oxidation stat is :

    Text Solution

    |

  21. Consider the following reaction A to P1, B to P2 , C to P3 , D to P4...

    Text Solution

    |