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An element with molar mas 2.7xx10^(-2)" ...

An element with molar mas `2.7xx10^(-2)" kg mol"^(-1)` forms a cubic unit cell with edge length 405 pm. If its density is `2.7xx10^(-3)kgm^(-3)`, the radius of the element is approximately ______ `xx 10^(-12) m` (to the nearest integer).

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To find the radius of the element given its molar mass, density, and edge length of the cubic unit cell, we can follow these steps: ### Step 1: Understand the relationship between density, molar mass, and the unit cell. The formula for density (d) is given by: \[ d = \frac{Z \cdot m}{a^3 \cdot N_A} \] where: - \( Z \) = number of atoms per unit cell - \( m \) = molar mass of the element - \( a \) = edge length of the cubic unit cell - \( N_A \) = Avogadro's number (approximately \( 6.022 \times 10^{23} \, \text{mol}^{-1} \)) ### Step 2: Rearrange the formula to solve for \( Z \). Rearranging the density formula gives: \[ Z = \frac{d \cdot a^3 \cdot N_A}{m} \] ### Step 3: Substitute the known values into the equation. Given: - \( d = 2.7 \times 10^{-3} \, \text{kg/m}^3 \) - \( a = 405 \, \text{pm} = 405 \times 10^{-12} \, \text{m} \) - \( m = 2.7 \times 10^{-2} \, \text{kg/mol} \) - \( N_A = 6.022 \times 10^{23} \, \text{mol}^{-1} \) Now substituting these values: \[ Z = \frac{(2.7 \times 10^{-3}) \cdot (405 \times 10^{-12})^3 \cdot (6.022 \times 10^{23})}{2.7 \times 10^{-2}} \] ### Step 4: Calculate \( a^3 \). Calculating \( a^3 \): \[ a^3 = (405 \times 10^{-12})^3 = 6.634 \times 10^{-28} \, \text{m}^3 \] ### Step 5: Substitute \( a^3 \) back into the equation for \( Z \). Now substituting \( a^3 \): \[ Z = \frac{(2.7 \times 10^{-3}) \cdot (6.634 \times 10^{-28}) \cdot (6.022 \times 10^{23})}{2.7 \times 10^{-2}} \] ### Step 6: Simplify and calculate \( Z \). Perform the calculations: \[ Z = \frac{(2.7 \times 10^{-3}) \cdot (6.634 \times 10^{-28}) \cdot (6.022 \times 10^{23})}{2.7 \times 10^{-2}} \approx 4 \] ### Step 7: Determine the type of cubic unit cell. Since \( Z = 4 \), the element likely belongs to a Face-Centered Cubic (FCC) structure. ### Step 8: Relate edge length \( a \) to atomic radius \( R \). For an FCC structure, the relationship between edge length \( a \) and atomic radius \( R \) is given by: \[ a = 2\sqrt{2}R \] Thus, we can rearrange this to find \( R \): \[ R = \frac{a}{2\sqrt{2}} \] ### Step 9: Substitute the value of \( a \) to find \( R \). Substituting \( a = 405 \times 10^{-12} \, \text{m} \): \[ R = \frac{405 \times 10^{-12}}{2\sqrt{2}} \approx 143.17 \times 10^{-12} \, \text{m} \] ### Step 10: Round the radius to the nearest integer. The radius \( R \) is approximately: \[ R \approx 143 \times 10^{-12} \, \text{m} \] ### Final Answer: The radius of the element is approximately \( 143 \times 10^{-12} \, \text{m} \). ---

To find the radius of the element given its molar mass, density, and edge length of the cubic unit cell, we can follow these steps: ### Step 1: Understand the relationship between density, molar mass, and the unit cell. The formula for density (d) is given by: \[ d = \frac{Z \cdot m}{a^3 \cdot N_A} \] where: ...
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