Consider the following equilibrium reaction at `327^(@)C`.
`A(g)+B(g)iffC(g)+D(l)`.
Which of the following option(s) is/are correct regarding `K_(p)` and `K_(c )` relationship ? [Given : 1/R = 12]

Options

A. `K_(c )=50 K_(p)`
B. `K_(p) lt L_(c )`
C. `K_(p) = K_(c )`
D. `K_(p) gt K_(c )`

Answer

B, C, D

Explanation

`SO_(2)(g)+NO_(2)(g)iffSO_(3)(g)+NO(g)`
`"mole 1 1 1 1"`
`because Q=1 gt K_(C )`
At equilibrium `"1+x 1+x 1-x 1-x"`
mole
`(1)/(16)=((1-x)/(1+x))^(2)implies (1-x)/(1+x)=(1)/(4)" "implies x=(3)/(5)`
`therefore [NO] =1-(3)/(5)=0.4, [NO_(2)] =1+(3
)/(5)=1.6`