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The rate consant for the forward reation...

The rate consant for the forward reation
`A(g) iff 2B(g)` is `1.5 xx 10^(-3)s^(-1)` at 300 K
If `10^(-5)` moles of A and 100 moles of B are present in 10L vessel at equilibrium, then select correct statement(s).

A

The rate constant of the backward reaction is greater than the rate constant of the forward reaction at given temperature.

B

The rate constant of the backward reaction is lesser than the rate constant of the forward reaction at given temperature.

C

The value of equilibrium constant `(K_(c ))` is `10^(-8)M`.

D

The value of rate constant of the backward direction at given temperature is `1.5 xx 10^(-11) M^(-1)S^(-1)`

Text Solution

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The correct Answer is:
B, D

`K=([B]^(2))/([A])=((100//10)^(2))/((10^(-5)//10))=(k_(f))/(k_(b))=(1.5 xx10^(-3))/(k_(b))=10^(8)thereforek_(b)=(1.5xx10^(-3)xx(10^(-6)))/(10^(2))=1.5 xx 10^(-11)`
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