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Amides with no substitution on nitrogen ...

Amides with no substitution on nitrogen react with tht: solution of bromine or chlorine in NaOH or KOH to yield aminei through a reaction called as Hofmann's degradation.
`R-overset(O)overset(||)(C )-NH_(2)+Br_(2)+4NaOH overset(H_(2)O)rarr R-NH_(2)+2NaBr+Na_(2)CO_(3)+2H_(2)O`
Amides can be reduced to amines having same number of carbon atoms
`R-overset(O)overset(||)C-NH_(2)-underset(LiAlH_(4))overset([H])toR-CH_(2)-NH_(2)`
will undergo Hofmann's degradation.

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Amides with no substitution on nitrogen react with tht: solution of bromine or chlorine in NaOH or KOH to yield aminei through a reaction called as Hofmann's degradation. R-overset(O)overset(||)(C )-NH_(2)+Br_(2)+4NaOH overset(H_(2)O)rarr R-NH_(2)+2NaBr+Na_(2)CO_(3)+2H_(2)O Amides can be reduced to amines having same number of carbon atoms R-overset(O)overset(||)C-NH_(2)-underset(LiAlH_(4))overset([H])toR-CH_(2)-NH_(2) N-Methyl aniline can be obtained by using Hofmann's degradation.

Amides with no substitution on nitrogen react with tht: solution of bromine or chlorine in NaOH or KOH to yield aminei through a reaction called as Hofmann's degradation. R-overset(O)overset(||)(C )-NH_(2)+Br_(2)+4NaOH overset(H_(2)O)rarr R-NH_(2)+2NaBr+Na_(2)CO_(3)+2H_(2)O Amides can be reduced to amines having same number of carbon atoms R-overset(O)overset(||)C-NH_(2)-underset(LiAlH_(4))overset([H])toR-CH_(2)-NH_(2) Iso-cyanates are formed as intermediate in the Hofmann's degradation.

R-overset(O)overset(||)C-NH_(2)underset(HCl)overset(NaNO_(2))rarr A A is :

R-overset(O)overset(||)(C ) -OH overset(H_(3)O^(+))(larr) X overset([H])(to) RCH_(2) NH_(2) X is ,

Me-overset(O)overset(||)C-O-CH_(2)-CH_(2)-overset(o+)NH_(2)overset(NaOH)rarr Q

NH_(2)-overset(O)overset(||)C-NH_(2) underset(Cl_(2))overset(NaOH)rarr Major product is :

OP TANDON-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Objective questions
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  2. The reactivity of acid derivatives in general follows the order: ...

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