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What is meant by the 'lanthanide contrac...

What is meant by the 'lanthanide contraction'? Mention one important fact that can be considered as a consequence of the lanthanide contraction.

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Lanthanide contraction phenomenon is associated with the intervenstion of the 4f orbitals which must be filled before the 5d series of elements begin. The filling of 4f before 5d orbita l results in a regular decrease in atomic radii called Lanthanoid contraction. This essentially compensates for the expected increase in atomic size with increasing atomic number. the net result of the lanthanoid contraction is that the second and the third d-series exhibit similar radii and have very similar physical and chemical properties.
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RESONANCE-D & F-BLOCK ELEMENTS & THEIR IMPORTANT COMPOUNDS -Exercise 1
  1. Write the electronic configurations of the following ions. (i). Mn^(...

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  2. Name the d-block element which do not have partially filled d-orbitals...

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  3. What is meant by the 'lanthanide contraction'? Mention one important f...

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  4. Name the (i) lightest and the (ii) heaviest element (in terms of densi...

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  5. Which element among d-block element has(i) the lowest melting point an...

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  6. Why Zinc has lowest melting point in 3d series?

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  7. Why are the ionisation energies of 5d elements greater than 3d element...

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  8. Why do transition elements show variable oxidation state?

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  9. What is the most common oxidation state of first transtion series.?

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  10. Name the three factors which determine the stability of a particular o...

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  11. Why is the E^(Theta) value for the Mn^(3+)//Mn^(2+) couple much postiv...

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  12. {:("Element",Cr,Mn,Fe),(E^(underset(-)(o))(M^(2+)//M),-0.90V,-1.18V,-0...

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  13. Which of the following ions would form (i) coloured and (ii) colourles...

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  14. Why Ti^(+4) complexes are diamagnetic?

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  15. A substance is found to have a magnetic moments of 3.9BM.How many unpa...

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  16. Explain giving reason: (a) Transition metals and many of their compo...

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  17. Describe the general characteristics of transition elements with speci...

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  18. Which type of reaction MnO(4)^(2-) shows with aid, dilute-alkali or wa...

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  19. Why KMnO(4) is stored in dark bottle and water happens to it's aidic s...

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  20. Why does AgNO(3) produce a black stain on the skin?

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