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What happens when: (a). Green vitriol ...

What happens when:
(a). Green vitriol is strongly heated.
(b). Malachite is made to react with dilute `H_(2)SO_(4)`
(c). Copper sulphate is exposed to air for longer period. ltBrgt (d). Lunar caustic is made to react with sodium hydroxide and then product is dried.
(e). Silver nitrate reacts with excess iodine.
(f). Potassium dichromate reacts with cold and concentrated `H_(2)SO_(4)`.

Text Solution

Verified by Experts

(a). `FeSO_(4).7H_(2)Ounderset(H_(2)O)overset(300^(@)C)toFeSO_(4)underset("tempt")overset(high)toFe_(2)O_(3)+SO_(2)+SO_(3)`
(b) `CuCO_(3).Cu(OH)_(2)+2H_(2)SO_(4)to2CuSO_(4)+3H_(2)O+CO_(2)uarr`
(c) `CuSO_(4).5H_(2)Ounderset("ettloresces")overset(air)toCuSO_(4).3H_(2)O`
(d) `2AgNO_(3)+2NaOHtoAg_(2)Odarr("black")+2NaNO_(3)+H_(2)O` ltbr (e). `5AgNO_(3)+3I_(2)("excess")+H_(2)OtoHIO_(3)+5AgIdarr("yellow")+5HNO_(3)`
(f) `K_(2)Cr_(2)O_(7)+2H_(2)SO_(4)(conc.&" "cold)to2CrO_(3)(red)+2KHSO_(4)+H_(2)O`
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RESONANCE-D & F-BLOCK ELEMENTS & THEIR IMPORTANT COMPOUNDS -Exercise 1
  1. Why is AgBr used in photography?

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  2. Why it is not advisable KMnO(4) in cold and concentrated H(2)SO(4)?

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  3. What happens when: (a). Green vitriol is strongly heated. (b). Mal...

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  4. State true or false: Reaction of K(2)Cr(2)O(7) with cold and concentra...

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  5. Write balaned chemical equations for: (i) Mixture of K(2)Cr(2)O(7) a...

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  6. What are inner-transition elements? Decide which of the following atom...

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  7. Actinoid contraction is greater from element to element than lanthanoi...

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  8. The chemistry of the actinoid elements is not so smooth as that of the...

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  9. Why Sm^(2+) , Eu^(2+) and Yb^(2+) ions in solution are good reducing a...

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  10. The transition elements have a general electronic configuration:

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  11. The atomic volume of the transition elements are low compared with ele...

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  12. The wrong statement regarding transition metals among the following is...

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  13. First IE of 5d seties element are higher than those of 3d and 4d serie...

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  14. Ionisation energies of Ni and Pt in KJmol^(-1) are given below {:(,u...

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  15. Maximum oxidation state is shown by:

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  16. Which of the following statement is false?

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  17. Which of the following has the maximum number of unpaired d-electron?

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  18. The highest magnetic moments is shown by the transition metal ion wit...

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  19. Magnetic moment of Cr^(+2)(Z=24),Mn^(+2)(Z=25) and Fe^(2+)(Z=26) are x...

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  20. The magnetic moment of .(25)Mn in ionic state is sqrt(15)B.M, then Mn ...

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