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The radius of calcium ion is 94 pm and o...

The radius of calcium ion is 94 pm and of oxide ion is 146pm. Predict the crystal structure of calcium oxide.

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The ratio `(r_(+))/(r_(-)) = (94)/(146) = 0.644`
The prediction is an octahedral arrangement of the oxide ions around the calcium. Because the ions have equal but opposite charges, there must also be an octahedral arrangement of calcium ions around oxide ions. Thus CaO structure is similar to Rock Salt (NaCl) structure.
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