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In a simple cubic lattice of anions, the...

In a simple cubic lattice of anions, the side length of the unit cell is `2.88 Å`. The diameter of the void in the body centre is

A

`1.934 Å`

B

`0.461Å`

C

`2.108Å`

D

`4.988Å`

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The correct Answer is:
To find the diameter of the void in the body center of a simple cubic lattice of anions, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Simple Cubic Lattice**: - In a simple cubic lattice, the anions are located at each corner of the cube. The body center of the cube is empty in a simple cubic structure. 2. **Identifying the Unit Cell Dimensions**: - The side length of the unit cell is given as \( a = 2.88 \, \text{Å} \). 3. **Determining the Radius of the Anion**: - In a simple cubic lattice, the anions touch each other along the edges of the cube. Therefore, the relationship between the side length \( a \) and the radius \( r \) of the anion is given by: \[ a = 2r \] - Rearranging this equation gives: \[ r = \frac{a}{2} = \frac{2.88 \, \text{Å}}{2} = 1.44 \, \text{Å} \] 4. **Finding the Diameter of the Void**: - The void in the body center of a simple cubic lattice is spherical and its diameter is equal to the distance between the centers of the anions located at the corners of the cube. - The distance between the centers of the anions at opposite corners of the cube can be calculated using the diagonal of the face of the cube: \[ \text{Diagonal of face} = a\sqrt{2} \] - The diameter of the void can be calculated as: \[ \text{Diameter of void} = \text{Diagonal of face} - 2r \] - Substituting the values: \[ \text{Diameter of void} = a\sqrt{2} - 2r = 2.88\sqrt{2} - 2(1.44) \] - Calculating \( 2.88\sqrt{2} \): \[ 2.88 \times 1.414 \approx 4.07 \, \text{Å} \] - Now substituting back: \[ \text{Diameter of void} = 4.07 - 2.88 \approx 1.19 \, \text{Å} \] ### Final Answer: The diameter of the void in the body center is approximately \( 1.19 \, \text{Å} \).
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