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Consider the following reactions: MX(4...

Consider the following reactions:
`MX_(4)+X'_(2) to MX_(4)X_(2)'`
If atomic number of M is 52 and X and X' are halogens and X' is more electonegative than X. The choose correct statemetn regarding given information:

A

Both X' atoms occupy axial positions which are formed by overlaping of p and d-orbitals only

B

All M-X bond lengths are identical in both `MX_(4) and MX_(4)X'_(2)` compounds

C

Central atom 'M' does not use anyone valence non-axial set of d-orbitals in hybridization of final product

D

Hybridization of central atom 'M' remains same in both reactant and final product

Text Solution

Verified by Experts

The correct Answer is:
C

`MX_(2)+X._(2) to MX_(4)X._(2)` (M=Te)
`to` Hybridisation of `Te: sp^(3)d^(2)(sp_(x)p_(y)p_(z)d_(x^(2)-y^(2))d_(x^(2)))`
`to` Axial position are formed by hybrid orbitals
`to` All M-X bond lengths are identical
`to` Hybridisation of `Te: sp^(3)d(sp_(x)p_(y)+p_(x)d_(x^(2)))`
``to` All M-X bond lengths are not identical
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VK JAISWAL-CHEMICAL BONDING (ADVANCED)-Level 2
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  2. Incorrect match is :

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  3. Consider the following reactions: MX(4)+X'(2) to MX(4)X(2)' If ato...

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  4. Select the correct statements:

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  10. In which of the following cases C-C bond length will be highest?

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  11. In which of the following cases C-C bond length will be highest? (I)...

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  13. Incorrect orders of bond angle is :

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  14. Minimum F-S-F bond angle present in :

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  15. The correct order of increasing bond angle is

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  16. The correct order of bond anlge is :

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  17. Which one is correct for bond angle?

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