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Which of the followimg complex compound(...

Which of the followimg complex compound(s) is/are paramagnetic and low spin? (I) `K_(3)[Fe(CN_(6))]`
(II) `[Ni(CO)_(4)]^(0)`
(III) `[Cr(NH_(3))_(6)]^(3+)`
(IV) `[Mn(CN)_(6)]^(4-)`

A

I only

B

II and III

C

I and IV

D

IV only

Text Solution

Verified by Experts

The correct Answer is:
C


`implies ` Low spin complex `mu=1.732` BM.
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Which of the following complexes are paramagnetic in nature ? [Fe(CN)_(6)]^(3-), [Fe(CN)_6]^(4-) , [CoF_6]^(3-), Ni(CO)_(4) .

The magnetic moment of complex given below are in the order: (I) [Ni(CO)_(4)] (II) [Mn(CN)_(6)]^(4-) (III) [Cr(NH_(3))_(6)]^(3+) (IV) [CoF_(6)]^(3-)

Which of the following is more stable ? (1) K_(4)[Fe(CN)_(6)] or K_(3)[Fe(CN)_(6)] (2) [Co(NH_(3))_(6)]^(3+) or [Co(en)_(2)(NH_(3))_(2)]^(3+) (3) [NiCl_(4)]^(2-) or [Ni(CN)_(4)]^(2-)

There are four complexes of Ni. Select the complexes/es which will be attracted by magnetic field : (I) [Ni(CN)_(4)]^(2-) (II) [NiCl_(4)]^(2-) (III) [Ni(CO)_(4)] (IV) [Ni(NH_(3))_(6)]^(2+)

VK JAISWAL-CO-ORDINATION COMPOUNDS-LEVEL 1
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  6. Which of the following is a low spin (spin-paired) complex?

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  16. The crystal field stabilisation energy of [Co(NH(3))(6)]Cl(3) is:

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  20. In the complex K(2)Fe[Fe(CN)(6)]:

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