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Aqueous solution of Ni^(2+) contains [Ni...

Aqueous solution of `Ni^(2+)` contains `[Ni(H_(2)O)_(6)]^(2+)` and its magnetic moment is 2.83 B.M. When ammonia is added in it, the predicted change in the magnetic moment of solution is:

A

It will remain same

B

it increases from 2.83 BM

C

it decreases from 2.83 BM

D

It cannot be predicated theoretically

Text Solution

Verified by Experts

The correct Answer is:
A

`underset(sp^(3)d^(2)" Hyb. ",mu_(e f f)=2.8BM)([Ni(H_(2)O)_(6)]^(2+))+6NH_(2) hArr underset(sp^(3)d^(2)" Hyb. "mu_(e f f)=2.8BM)([Ni(NH_(3))_(6)]^(2+))+6H_(2)O`
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