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The pi acid ligand which uses it d-orbit...

The `pi` acid ligand which uses it d-orbital during synergic bonding in its complex compound.

A

`CN^(-)`

B

`PR_(3)`

C

`NO`

D

`N_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

Vaccant non-axial d-orbital participiate in `M overset(pi)toPR_(3)` back bonding in its complexes.
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The pi -acid ligand which uses its d-orbital during synergic bonding in its complex compound:

Which of the following involves synergic bonding?

Two important physical evidences supporting the synergic bonding in non-classical complexes are bond lengths and vibrational spectra. Vibrational spectra is based on the fact that the compression and extension of a bond may be analogous to the behaviour of a spring and obeys Hook's law. overline(v)=(1)/(2pic)sqrt((k)/(mu))cm^(-1) where, k=force force constant of the bond which is directly proportional to bonnd strength of CO mu= reduced mass of ligand overline(v) =stretching frequency of the CO bond c=velocity of light Q. In which of the following ligand, sigma -bond order does not change during synergic bonding in their respective complexes:

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