Home
Class 12
CHEMISTRY
Which of the following statement is not ...

Which of the following statement is not true for the reaction given below:
`[Cu(H_(2)O)_(4)]^(2+)+ 4NH_(4) hArr [Cu(NH_(3))_(4)]^(2+)+4H_(2)O`

A

It is ligand substitution reaction

B

`NH_(3)` is a relatively strong field ligand while `H_(2)O` is a weak field ligand

C

During the reaction, there is a change in colour from light blue to dark blue

D

`[Cu(NH_(3))_(4)]^(2+)`, has a tetrahedral structure and is paramagnetic

Text Solution

Verified by Experts

The correct Answer is:
B

In `[Cu(NH_(3))_(4)]^(2+),Cu^(2+)` is `dsp^(2)` hybridised, hence square is square planar and complex is paramagnetic.
Promotional Banner

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    VK JAISWAL|Exercise ONE OR MORE ANSWERS IS/ARE CORRECT|72 Videos
  • CO-ORDINATION COMPOUNDS

    VK JAISWAL|Exercise MATCH THE COLUMN|36 Videos
  • CHEMICAL BONDING (BASIC)

    VK JAISWAL|Exercise Level 3 (Passive 11)|6 Videos
  • d-BLOCK ELEMENTS

    VK JAISWAL|Exercise SUBJECTIVE PROBLEMS|6 Videos

Similar Questions

Explore conceptually related problems

Which of the following statements is (are) correct about the reaction given below ? NH_(4)OH + HCI to NH_(4) CI +H_(2)O

CuSO_(4)+NH_(3)(excess) to [Cu(NH_(3))_(4)]^(2+)

The shape of [Cu(NH_(3))_(4)]^(2+) is

Which of the following reactions is a redox reaction? (a). CuSO_(4)+4NH_(3) to [Cu(NH_(3))_(4)]SO_(4) (b). Na_(2)SO_(4)+BaCl_(2) to BaSO_(4)+2NaCl (c ). SO_(2)+H_(2)O to H_(2)SO_(4) (d). 2CuSO_(4)+4KI to Cu_(2)I_(2)+2K_(2)SO_(4)+I_(2)

Cu(OH)_(2)darr+4NH_(3)("soln.")to[Cu(NH_(3))_(4)]^(2+)+2OH^(-)

VK JAISWAL-CO-ORDINATION COMPOUNDS-ASSERTION-REASON TYPE QUESTIONS
  1. Which of the following statement is not true for the reaction given be...

    Text Solution

    |

  2. Assertion: In N(2) Molecule, any N-atom can coordinate with central at...

    Text Solution

    |

  3. Assertion: In N(2)H(4), any one N-atom can coordination with central m...

    Text Solution

    |

  4. These questions consist of two statements each, printed as Assertion a...

    Text Solution

    |

  5. Assertion: Acidified [Cu(NH(3))(4)]^(2+) and [Cu(H(2)O)(4)]^(2+) both ...

    Text Solution

    |

  6. Assertion: [Fe(EDTA)]^(-) complex is octahedral in shape. Reason: ED...

    Text Solution

    |

  7. STATEMENT-1: Tetrahedral complexes with chiral structure exhibit optic...

    Text Solution

    |

  8. Assertion: Oxidation state of Fe in Fe(CO)(5) is zero. Reason: Syner...

    Text Solution

    |

  9. Assertion: Zeise's salt is a pi-bonded organometallic compound. Reas...

    Text Solution

    |

  10. Assertion: [ClCl(3)(NH(3))(3)] does not give white precipitate with Ag...

    Text Solution

    |

  11. Assertion: Transition metal ion forming octahedral complexes undergo s...

    Text Solution

    |

  12. Assertion: Complex ion [Co(NH(3))(6)]^(2+) is readily oxidized to [Co(...

    Text Solution

    |

  13. Assertion: Hydrazine is a neutral ligand. Reason: It has two N as do...

    Text Solution

    |

  14. Reason: Complex anion [Re(2)Cl(8)]^(2-) has one delta-bond, one sigma ...

    Text Solution

    |

  15. Assertion: In N(2) Molecule, any N-atom can coordinate with central at...

    Text Solution

    |

  16. Assertion: In N(2)H(4), any one N-atom can coordination with central m...

    Text Solution

    |

  17. Assertion: [Ti(H(2)O)(6)]^(4+) is coloured while [Sc(H(2)O)(6)]^(3+) i...

    Text Solution

    |

  18. Assertion: Acidified [Cu(NH(3))(4)]^(2+) and [Cu(H(2)O)(4)]^(2+) both ...

    Text Solution

    |

  19. Assertion: [Fe(EDTA)]^(-) complex is octahedral in shape. Reason: ED...

    Text Solution

    |

  20. Assertion: Tetrahedral complexes with chiral structure exhibit optical...

    Text Solution

    |

  21. Assertion: Oxidation state of Fe in Fe(CO)(5) is zero. Reason: Syner...

    Text Solution

    |