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Which of the following statement is true...

Which of the following statement is true?

A

In `[PtCl_(2)(NH_(3))_(2)]^(2+)` the cis form is optically inactive while trans form is optically active

B

In `[Fe(C_(2)O_(4))_(3)]^(3-)`, geometrical isomerism does not exist while optical isomerism exists

C

In Mabcd, square planar complexes show both optical as well as geometrical isomerism

D

In Mabcd tetrahedral compoex, optical isomerism cannot be observed

Text Solution

Verified by Experts

The correct Answer is:
C


Above configuration is asymmetrical, hence optically active. Mabcd square planar exhibits geometricl isomerism Mabcd tetrahedral complex is optically active.
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VK JAISWAL-CO-ORDINATION COMPOUNDS-ASSERTION-REASON TYPE QUESTIONS
  1. Which of the following statement is true?

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  2. Assertion: In N(2) Molecule, any N-atom can coordinate with central at...

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  3. Assertion: In N(2)H(4), any one N-atom can coordination with central m...

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  4. These questions consist of two statements each, printed as Assertion a...

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  5. Assertion: Acidified [Cu(NH(3))(4)]^(2+) and [Cu(H(2)O)(4)]^(2+) both ...

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  6. Assertion: [Fe(EDTA)]^(-) complex is octahedral in shape. Reason: ED...

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  7. STATEMENT-1: Tetrahedral complexes with chiral structure exhibit optic...

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  8. Assertion: Oxidation state of Fe in Fe(CO)(5) is zero. Reason: Syner...

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  9. Assertion: Zeise's salt is a pi-bonded organometallic compound. Reas...

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  10. Assertion: [ClCl(3)(NH(3))(3)] does not give white precipitate with Ag...

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  11. Assertion: Transition metal ion forming octahedral complexes undergo s...

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  12. Assertion: Complex ion [Co(NH(3))(6)]^(2+) is readily oxidized to [Co(...

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  13. Assertion: Hydrazine is a neutral ligand. Reason: It has two N as do...

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  14. Reason: Complex anion [Re(2)Cl(8)]^(2-) has one delta-bond, one sigma ...

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  15. Assertion: In N(2) Molecule, any N-atom can coordinate with central at...

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  16. Assertion: In N(2)H(4), any one N-atom can coordination with central m...

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  17. Assertion: [Ti(H(2)O)(6)]^(4+) is coloured while [Sc(H(2)O)(6)]^(3+) i...

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  18. Assertion: Acidified [Cu(NH(3))(4)]^(2+) and [Cu(H(2)O)(4)]^(2+) both ...

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  19. Assertion: [Fe(EDTA)]^(-) complex is octahedral in shape. Reason: ED...

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  20. Assertion: Tetrahedral complexes with chiral structure exhibit optical...

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  21. Assertion: Oxidation state of Fe in Fe(CO)(5) is zero. Reason: Syner...

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