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In the given reaction sequence CH3CHO ...

In the given reaction sequence
`CH_3CHO underset((ii)H_2O^+)overset((i) NaCN//HCl)(rarr)(A) underset("reagent")overset("Fenton")(rarr)(B)`, B will be

A

Acetic acid

B

Oxalic acid

C

Pyruvic acid

D

Citric acid

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The correct Answer is:
To solve the given reaction sequence, we will break down the steps involved in the transformation of the reactant to the final product. ### Step-by-Step Solution: 1. **Identify the Starting Material:** The starting material is **CH₃CHO**, which is acetaldehyde (an aldehyde). 2. **Nucleophilic Addition Reaction:** The first step involves the reaction of acetaldehyde with **NaCN** in the presence of **HCl**. Here, the cyanide ion (CN⁻) acts as a nucleophile and attacks the electrophilic carbon of the carbonyl group in acetaldehyde. - The reaction can be represented as: \[ CH₃CHO + CN⁻ \rightarrow CH₃C(OH)(CN) \] - This forms a cyanohydrin intermediate, which is **2-hydroxy-2-methylpropanenitrile**. 3. **Protonation:** The intermediate formed is then protonated by **H₂O** (from HCl), leading to the formation of **lactic acid** (A): \[ CH₃C(OH)(CN) + H₂O \rightarrow CH₃C(OH)(COOH) \] - This compound is **lactic acid** (2-hydroxypropanoic acid). 4. **Oxidation with Fenton's Reagent:** Next, lactic acid (A) is treated with **Fenton's reagent**, which is a combination of hydrogen peroxide (H₂O₂) and ferrous iron (Fe²⁺). This reagent is known for its oxidizing properties. - The oxidation of lactic acid will convert the hydroxyl group (-OH) into a carbonyl group (C=O), resulting in the formation of **pyruvic acid** (B): \[ CH₃C(OH)(COOH) \xrightarrow{Fenton's} CH₃C(=O)COOH \] - The product formed is **pyruvic acid** (2-oxopropanoic acid). ### Final Answer: Thus, the compound B formed in the reaction sequence is **pyruvic acid**.
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