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If x mole of ideal gas at 27^(@)C expand...

If x mole of ideal gas at `27^(@)C` expands isothermally and reversibly from a volume of y to 10 y, then the work done is

A

`w = x R 300 In y`

B

`w = -300 x R In y/10y`

C

`w = - 300 x R ln 10`

D

`w = 100 x R In 1/y`

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The correct Answer is:
To solve the problem of calculating the work done during the isothermal and reversible expansion of an ideal gas, we can follow these steps: ### Step-by-Step Solution 1. **Identify Given Values:** - Number of moles (n) = x moles - Initial volume (V1) = y - Final volume (V2) = 10y - Temperature (T) = 27°C = 27 + 273 = 300 K 2. **Understand the Work Done Formula:** - For an isothermal and reversible expansion of an ideal gas, the work done (W) is given by the formula: \[ W = -nRT \ln\left(\frac{V_2}{V_1}\right) \] - Here, R is the universal gas constant. 3. **Substitute the Known Values:** - Substitute n = x, R (approximately 8.314 J/(mol·K)), T = 300 K, V2 = 10y, and V1 = y into the formula: \[ W = -x \cdot R \cdot 300 \cdot \ln\left(\frac{10y}{y}\right) \] 4. **Simplify the Logarithm:** - The logarithm simplifies as follows: \[ \ln\left(\frac{10y}{y}\right) = \ln(10) \] - Therefore, the equation for work done becomes: \[ W = -x \cdot R \cdot 300 \cdot \ln(10) \] 5. **Final Expression:** - Substitute R into the equation: \[ W = -300xR \ln(10) \] - This is the final expression for the work done during the isothermal expansion. ### Final Answer: \[ W = -300xR \ln(10) \]
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