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For reaction 2A+B hArr 2C, K=x Equilib...

For reaction `2A+B hArr 2C, K=x`
Equilibrium constant for `C hArr A+1//2 B` will be

A

x

B

`x/2`

C

`1/sqrtx`

D

`sqrtx`

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The correct Answer is:
To find the equilibrium constant for the reaction \( C \rightleftharpoons A + \frac{1}{2}B \) in terms of the equilibrium constant \( K \) for the reaction \( 2A + B \rightleftharpoons 2C \), where \( K = x \), we can follow these steps: ### Step 1: Write the given reaction and its equilibrium expression The given reaction is: \[ 2A + B \rightleftharpoons 2C \] The equilibrium constant \( K \) for this reaction is given by: \[ K = \frac{[C]^2}{[A]^2[B]} \] Given that \( K = x \), we can write: \[ x = \frac{[C]^2}{[A]^2[B]} \] ### Step 2: Write the reverse reaction and its equilibrium expression Now, we need to consider the reverse reaction: \[ C \rightleftharpoons A + \frac{1}{2}B \] The equilibrium constant \( K' \) for this reaction can be expressed as: \[ K' = \frac{[A][B]^{1/2}}{[C]} \] ### Step 3: Relate the two equilibrium constants To relate \( K' \) to \( K \), we can use the fact that reversing a reaction inverts the equilibrium constant. Additionally, when we change the coefficients of a reaction, the equilibrium constant is raised to the power of the coefficient. For the reaction \( 2A + B \rightleftharpoons 2C \), when we reverse it, we get: \[ C \rightleftharpoons A + \frac{1}{2}B \] This is equivalent to taking the square root of the original equilibrium constant because the coefficients are halved. Therefore: \[ K' = \frac{1}{\sqrt{x}} \] ### Step 4: Final expression for the equilibrium constant Thus, the equilibrium constant for the reaction \( C \rightleftharpoons A + \frac{1}{2}B \) is: \[ K' = \frac{1}{\sqrt{x}} \] ### Conclusion The equilibrium constant for the reaction \( C \rightleftharpoons A + \frac{1}{2}B \) in terms of \( x \) is: \[ \boxed{\frac{1}{\sqrt{x}}} \]
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