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A salt of strong acid and weak base is d...

A salt of strong acid and weak base is dissolved in water. Its hydrolysis in solution is

A

Unaffected on heating

B

increased by adding strong acid

C

Suppressed by diluting

D

Suppressed by adding strong acid

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The correct Answer is:
To solve the question regarding the hydrolysis of a salt formed from a strong acid and a weak base when dissolved in water, we can follow these steps: ### Step 1: Identify the Components - A salt formed from a strong acid (e.g., HCl) and a weak base (e.g., NH₄OH) will dissociate in water to give its constituent ions. - For example, the salt NH₄Cl will dissociate into NH₄⁺ and Cl⁻ ions. ### Step 2: Understand Hydrolysis - Hydrolysis is the reaction of the ions with water. In this case, the weak base (NH₄⁺) will undergo hydrolysis. - The hydrolysis of NH₄⁺ can be represented as: \[ NH₄^+ + H₂O \rightleftharpoons NH₃ + H₃O^+ \] - This reaction shows that NH₄⁺ ions react with water to produce NH₃ (ammonia) and H₃O⁺ (hydronium ion). ### Step 3: Analyze the Effect of Strong Acid - Since the acid is strong, it will completely dissociate in solution, contributing a significant amount of H₃O⁺ ions. - The presence of H₃O⁺ ions will shift the equilibrium of the hydrolysis reaction to the left according to Le Chatelier's principle, suppressing the hydrolysis of the weak base. ### Step 4: Conclusion - The hydrolysis of the salt (NH₄Cl) is suppressed due to the addition of the strong acid, which increases the concentration of H₃O⁺ ions in the solution. - Therefore, the final conclusion is that the hydrolysis of the salt is suppressed by the strong acid. ### Final Answer The hydrolysis of a salt formed from a strong acid and a weak base in solution is suppressed by the addition of the strong acid. ---
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