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Which compound acts as oxidising agent o...

Which compound acts as oxidising agent only?

A

`SO_(2)`

B

`H_(2)S`

C

`H_(2)SO_(4)`

D

`HNO_(2)`

Text Solution

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The correct Answer is:
To determine which compound acts as an oxidizing agent only, we need to analyze the oxidation states of the elements in various compounds. An oxidizing agent is a substance that gains electrons (is reduced) and, in the process, causes another substance to be oxidized. ### Step-by-Step Solution: 1. **Identify the Compounds**: We need to consider various compounds and their oxidation states. For this example, let’s analyze sulfur dioxide (SO₂) and sulfuric acid (H₂SO₄). 2. **Calculate Oxidation State of Sulfur in SO₂**: - In SO₂, oxygen has an oxidation state of -2. - The total oxidation state for two oxygen atoms = 2 × (-2) = -4. - Let the oxidation state of sulfur be x. The overall charge of the molecule is 0. - Therefore, the equation is: \[ x + (-4) = 0 \implies x = +4 \] - Thus, the oxidation state of sulfur in SO₂ is +4. 3. **Calculate Oxidation State of Sulfur in H₂SO₄**: - In H₂SO₄, hydrogen has an oxidation state of +1 and oxygen is -2. - The total oxidation state for four oxygen atoms = 4 × (-2) = -8. - Let the oxidation state of sulfur be y. The overall charge of the molecule is 0. - Therefore, the equation is: \[ 2(+1) + y + 4(-2) = 0 \implies 2 + y - 8 = 0 \implies y = +6 \] - Thus, the oxidation state of sulfur in H₂SO₄ is +6. 4. **Identify the Oxidizing Agent**: - An oxidizing agent is typically a species with a higher oxidation state that can accept electrons. - In this case, sulfur in H₂SO₄ has a higher oxidation state (+6) compared to sulfur in SO₂ (+4). - Therefore, H₂SO₄ acts as an oxidizing agent. 5. **Conclusion**: - Among the compounds analyzed, H₂SO₄ is the one that acts as an oxidizing agent only due to the higher oxidation state of sulfur.
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