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Oxidation numbers of A, B, C are +2, +5 ...

Oxidation numbers of A, B, C are +2, +5 and -2 respectively. Possible formula of compound is

A

`A_(2)(BC_(2))_(2)`

B

`A_(3)(BC_(4))_(2)`

C

`A_(2)(BC_(3))_(2)`

D

`A_(3)(B _(2)C_(2))`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the possible formula of a compound formed by elements A, B, and C with oxidation numbers +2, +5, and -2 respectively, we need to ensure that the overall charge of the compound is neutral (i.e., the total positive charge equals the total negative charge). ### Step-by-Step Solution: 1. **Identify Oxidation States:** - A has an oxidation number of +2. - B has an oxidation number of +5. - C has an oxidation number of -2. 2. **Set Up the Charge Balance Equation:** - Let the number of atoms of A be \( x \), the number of atoms of B be \( y \), and the number of atoms of C be \( z \). - The total positive charge from A and B must equal the total negative charge from C for the compound to be neutral. - The equation can be written as: \[ 2x + 5y - 2z = 0 \] 3. **Choose Values for x, y, and z:** - We need to find integer values for \( x \), \( y \), and \( z \) that satisfy the charge balance equation. - Let's try \( x = 1 \), \( y = 1 \), and \( z = 2 \): \[ 2(1) + 5(1) - 2(2) = 2 + 5 - 4 = 3 \quad (\text{not neutral}) \] - Now, let's try \( x = 2 \), \( y = 1 \), and \( z = 2 \): \[ 2(2) + 5(1) - 2(2) = 4 + 5 - 4 = 5 \quad (\text{not neutral}) \] - Next, let's try \( x = 2 \), \( y = 1 \), and \( z = 5 \): \[ 2(2) + 5(1) - 2(5) = 4 + 5 - 10 = -1 \quad (\text{not neutral}) \] - Finally, let's try \( x = 2 \), \( y = 1 \), and \( z = 3 \): \[ 2(2) + 5(1) - 2(3) = 4 + 5 - 6 = 3 \quad (\text{not neutral}) \] - After several trials, we find that \( x = 3 \), \( y = 2 \), and \( z = 8 \): \[ 2(3) + 5(2) - 2(8) = 6 + 10 - 16 = 0 \quad (\text{neutral}) \] 4. **Write the Formula:** - The formula based on the coefficients we found is \( A_3B_2C_8 \). ### Final Answer: The possible formula of the compound is \( A_3B_2C_8 \).
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