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A : When Cu(2)S is converted into Cu^(++...

A : When `Cu_(2)S` is converted into `Cu^(++)" & " SO_(2)`, then equivalent weight of `Cu_(2)S` will be M/8 (M = Mol. wt. of `Cu_(2)S`)
R : `Cu^(+)` is converted `Cu^(++)`, during this one electrons is lost.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To determine the equivalent weight of \( \text{Cu}_2\text{S} \) when it is converted into \( \text{Cu}^{2+} \) and \( \text{SO}_2 \), we need to analyze the changes in oxidation states and calculate the valency factor. ### Step-by-Step Solution: 1. **Identify the Oxidation States**: - In \( \text{Cu}_2\text{S} \), copper (Cu) is in the +1 oxidation state and sulfur (S) is in the -2 oxidation state. - When \( \text{Cu}_2\text{S} \) is converted to \( \text{Cu}^{2+} \) and \( \text{SO}_2 \), the oxidation states change as follows: - Copper changes from +1 to +2 (each Cu atom). - Sulfur changes from -2 in \( \text{Cu}_2\text{S} \) to +4 in \( \text{SO}_2 \). 2. **Calculate the Change in Oxidation States**: - For Copper: - Each Cu changes from +1 to +2, which is an increase of 1 for each of the 2 Cu atoms: \( 2 \times (2 - 1) = 2 \). - For Sulfur: - Sulfur changes from -2 to +4, which is an increase of 6: \( 4 - (-2) = 6 \). 3. **Determine the Total Change in Electrons**: - Total change in electrons = Change for Cu + Change for S = \( 2 + 6 = 8 \). 4. **Calculate the Valency Factor**: - The valency factor (n) is the total change in electrons, which we found to be 8. 5. **Calculate the Equivalent Weight**: - The equivalent weight of a substance is given by the formula: \[ \text{Equivalent Weight} = \frac{\text{Molecular Weight}}{\text{Valency Factor}} \] - Therefore, for \( \text{Cu}_2\text{S} \): \[ \text{Equivalent Weight} = \frac{M}{8} \quad \text{(where M is the molar mass of } \text{Cu}_2\text{S)} \] 6. **Conclusion**: - The assertion that the equivalent weight of \( \text{Cu}_2\text{S} \) will be \( \frac{M}{8} \) is correct. - The reasoning that \( \text{Cu}^+ \) is converted to \( \text{Cu}^{2+} \) by losing one electron is also correct. ### Final Answer: - Both the assertion (A) and reasoning (R) are correct.
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