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The correct relation for radius of atom ...

The correct relation for radius of atom and edge - length in case of fcc arrangement is

A

`r=(a)/(2)`

B

`r=(sqrt(3)a)/(4)`

C

`r=(a)/(2sqrt(2))`

D

`r=(4a)/(sqrt(3))`

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The correct Answer is:
To find the correct relation between the radius of an atom (r) and the edge length (a) in a face-centered cubic (FCC) arrangement, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding FCC Structure**: In a face-centered cubic (FCC) arrangement, atoms are located at each of the corners of the cube and at the center of each face. 2. **Visualizing the Face Diagonal**: To find the relationship between the radius and edge length, we will consider the face diagonal of the cube. The face diagonal connects two corners of a face and passes through the center atom. 3. **Setting Up the Geometry**: Let's denote the edge length of the cube as \( a \). Each side of the face forms a right triangle with the face diagonal. The face diagonal can be calculated using the Pythagorean theorem. 4. **Calculating the Face Diagonal**: The length of the face diagonal (d) can be calculated as: \[ d = \sqrt{a^2 + a^2} = \sqrt{2a^2} = a\sqrt{2} \] 5. **Identifying the Atoms on the Face Diagonal**: On the face diagonal, there are three atoms contributing to the total length: one at each corner and one at the face center. Each corner atom contributes a radius \( r \), and the face-centered atom contributes another radius \( r \). 6. **Setting Up the Equation**: The total length of the face diagonal can be expressed in terms of the radius: \[ d = 4r \] Therefore, we can equate the two expressions for the face diagonal: \[ a\sqrt{2} = 4r \] 7. **Solving for the Radius**: Rearranging the equation to solve for \( r \): \[ r = \frac{a\sqrt{2}}{4} \] 8. **Simplifying the Expression**: To simplify further, we can express \( r \) as: \[ r = \frac{a}{2\sqrt{2}} \] ### Conclusion: The correct relation for the radius of an atom and the edge length in the case of an FCC arrangement is: \[ r = \frac{a}{2\sqrt{2}} \]
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AAKASH INSTITUTE-THE SOLID STATE -EXERCISE
  1. The number of tetrahedral voids present on each body diagonal ccp unit...

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  2. Octahedral void at edge center in ccp arrangement is equally distribut...

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  3. Total number of octahedral voids present per unit cell of ccp unit cel...

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  4. The co-ordination number in 3D-hexagonal close packing is

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  5. The efficiency of packing in simple cubic unit cell is

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  6. 'A' has fcc arrangement, 'B' is present in 2//3^(rd) of tetrahedral vo...

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  7. Gold crystallises in ccp structure. The number of voids present in 197...

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  8. The correct relation for radius of atom and edge - length in case of f...

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  9. The type of void present at the centre of the ccp unit cell is

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  10. The ratio of atoms present per unit cell in bcc to that present in fcc...

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  11. Stoichiometric defect is also known as

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  12. Which one of the following compounds can show Frenkel defect ?

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  13. In NaCl there are schottky pairs per cm^(3) at room temperature

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  14. Which of the following compounds is likely to show both Frenkel a...

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  15. The anionic sites occupied by electrons are called

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  16. The solids which are good conductor of electricity should have conduct...

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  17. Identify the antiferromagnetic substance

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  18. n-type semiconductor is

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  19. Which of the following substance is diamagnetic ?

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  20. Metal excess defect arises due to

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