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A unit cell is obtained by closed packin...

A unit cell is obtained by closed packing layers of atoms in ABAB …… pattern. The total number of tetrahedral and octahedral voids in the unit cell are respectively

A

6, 12

B

8, 4

C

4, 8

D

12, 6

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The correct Answer is:
To solve the problem of finding the total number of tetrahedral and octahedral voids in a unit cell with an ABAB... closed packing pattern, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Type of Packing**: - The given packing pattern is ABAB..., which corresponds to hexagonal close packing (HCP). 2. **Determine the Number of Atoms per Unit Cell (Z)**: - In hexagonal close packing, the number of atoms per unit cell (Z) is 6. 3. **Use the Formulas for Voids**: - The number of tetrahedral voids (T) and octahedral voids (O) can be calculated using the following formulas: - Tetrahedral voids = 2n (where n is the number of atoms in the unit cell) - Octahedral voids = n 4. **Calculate the Number of Tetrahedral Voids**: - Since Z = 6 (n = 6), the number of tetrahedral voids is: \[ T = 2n = 2 \times 6 = 12 \] 5. **Calculate the Number of Octahedral Voids**: - The number of octahedral voids is: \[ O = n = 6 \] 6. **Final Result**: - Therefore, the total number of tetrahedral voids is 12 and the total number of octahedral voids is 6. ### Summary: - Tetrahedral voids = 12 - Octahedral voids = 6
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