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A : In Schottky defect, density of cryst...

A : In Schottky defect, density of crystal decreases.
R : Equal number of cations and anions are missing in Schottky defect.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false then mark (3)

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given statements regarding Schottky defects, we will break down the assertion (A) and reason (R) step by step. ### Step-by-Step Solution: 1. **Understanding Schottky Defect**: - A Schottky defect is a type of point defect in a crystal lattice where an equal number of cations and anions are missing from their lattice sites. This defect maintains the stoichiometry of the compound. 2. **Assertion Analysis (A)**: - The assertion states that "In Schottky defect, density of crystal decreases." - When cations and anions are missing, the overall mass of the crystal decreases while the volume remains the same. Since density is defined as mass per unit volume (Density = Mass/Volume), a decrease in mass while volume remains constant results in a decrease in density. 3. **Reason Analysis (R)**: - The reason states that "Equal number of cations and anions are missing in Schottky defect." - This statement is true. In a Schottky defect, the loss of cations and anions occurs in equal numbers to maintain the overall charge neutrality of the crystal. 4. **Conclusion**: - Both the assertion (A) and the reason (R) are true. The assertion correctly describes the effect of Schottky defects on crystal density, and the reason accurately explains the nature of the defect. ### Final Answer: - Both A and R are true, and R is the correct explanation of A. ---
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AAKASH INSTITUTE-THE SOLID STATE -Assignment (SECTION - D) (ASSERTION-REASON TYPE QUESTION)
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  2. A : The co - ordination number of CaF(2) is 8 : 4. R : Ca^(2+) ion...

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  3. A : The number of spheres are equal to the number of octahedral voids ...

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  4. A : In Schottky defect, density of crystal decreases. R : Equal nu...

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  5. A : If a tetrad axis is passed through the unit cell of NaCl and all i...

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  6. A : A particle at the corner of CCP unit cell has (1)/(8)th of its con...

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  7. A : Glass belongs to the category of covalent network solid. R : U...

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  8. A : NaCl shows Schottky defect at room temperature. R : NaCl shows...

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  9. A : Fe(3)O(4) is ferrimagnetic at room temperature but becomes paramag...

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  10. A : In molecular solids the lattice points are occupied by the atoms o...

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  11. A : Silicon is insulator at 0 K but semiconductor at room temperature....

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  12. A : Amorphous solids are isotropic. R : Amorphous solids are not rig...

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  13. A : In NaCl coordination number of Cl^(-) ion is 6 but in CsCl coordin...

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  14. A : All crystals of same substance possess the same elements of symmet...

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  15. A : AgBr shows both Schottky and Frenkel defect. R : AgBr is a cry...

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  16. A : Number of carbon atoms per unit cell in diamond is 8. R : The ...

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  17. A : The coordination number of ionic compound depends upon radius rati...

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  18. A : Number of rectangular plane in a cubic crystal is 3. R : Recta...

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  19. A : ccp is more efficient than hcp. R : Packing fraction is differe...

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  20. A : Coordination number of both Na^(+) and Cl^(-) NaCl is 6. R : Se...

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