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A : If a tetrad axis is passed through t...

A : If a tetrad axis is passed through the unit cell of NaCl and all ions removed which are touching to tetrad axis then the formula of NaCl becomes `Na_(3)Cl_(4)`.
R : Only one `Na^(+)` is removed not the `Cl^(-)`.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false then mark (3)

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the assertion (A) and reason (R) given in the question regarding the unit cell of NaCl when a tetrad axis is passed through it. ### Step-by-Step Solution: 1. **Understanding the Structure of NaCl**: - NaCl crystallizes in a face-centered cubic (FCC) structure. - In one unit cell of NaCl, there are: - 8 Na⁺ ions at the corners (each contributes 1/8 to the unit cell). - 6 Na⁺ ions at the face centers (each contributes 1/2 to the unit cell). - 1 Na⁺ ion at the body center (contributes 1 to the unit cell). - Total contribution of Na⁺ ions = \(8 \times \frac{1}{8} + 6 \times \frac{1}{2} + 1 = 1 + 3 + 1 = 5\). 2. **Counting Cl⁻ Ions**: - Similarly, for Cl⁻ ions: - 8 Cl⁻ ions at the corners (each contributes 1/8). - 6 Cl⁻ ions at the face centers (each contributes 1/2). - Total contribution of Cl⁻ ions = \(8 \times \frac{1}{8} + 6 \times \frac{1}{2} = 1 + 3 = 4\). 3. **Identifying the Tetrad Axis**: - A tetrad axis is also known as a cube diagonal. - On the cube diagonal, there will be: - 2 corner ions (which are Cl⁻) and 1 body-centered ion (which is Na⁺). 4. **Removing Ions Touching the Tetrad Axis**: - When we remove the ions that touch the tetrad axis: - We remove 2 Cl⁻ ions from the corners. - We remove 1 Na⁺ ion from the body center. - After removal: - Remaining Na⁺ ions = \(5 - 1 = 4\). - Remaining Cl⁻ ions = \(4 - 2 = 2\). 5. **Calculating the New Formula**: - After the removal, we have: - Na⁺ = 4 - Cl⁻ = 2 - Therefore, the new formula becomes \(Na_4Cl_2\). 6. **Conclusion**: - The assertion (A) states that the formula becomes \(Na_3Cl_4\), which is incorrect. - The reason (R) states that only one Na⁺ is removed and not Cl⁻, which is also incorrect since two Cl⁻ ions are removed. - Thus, both the assertion and reason are false. ### Final Answer: - The new formula after removing the ions touching the tetrad axis is \(Na_4Cl_2\). - Both the assertion and reason are false.
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