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In which one of the following pairs the ...

In which one of the following pairs the two speccies have identical shape, but differ in hybridisation?

A

`l_(3)^(-),BeCl_(2)`

B

`NH_(3),BF_(3)`

C

`XeF_(2),l_(3)^(-)`

D

`NH_(4)^(+),SF_(4)`

Text Solution

Verified by Experts

The correct Answer is:
A

In the ions, halogen atom larger in size like `l_(3)^(-)` undergoes `sp^(3)d` hybridisation giving a linear shape with three lone pairs at equatorial positions. Beryllium chloride has linear structure with sp hybridisation.
`:underset("..")overset("..")(Cl) - Be - underset(" ..")overset(". .")(Cl):`
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