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Give evidence that [Co(NH(3))(5)Cl]SO(4)...

Give evidence that `[Co(NH_(3))_(5)Cl]SO_(4) and [Co(NH_(3))_(5)SO_(4)]Cl` are ionization isomers.

Text Solution

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The ionisation isomers dissolve in water to yield different ions and thus react differently to various reagents:
`[Co(NH_(3))_(5)Br]SO_(4)+Ba^(2+)rarr BaSO_(4)(s)`
`[Co(NH_(3))_(5)SO_(4)]Br+Ba^(2+)rarr"No reaction"`
`[Co(NH_(3))_(5)Br]SO_(4)+Ag^(+)rarr "No reaction"`
`[Co(NH_(3))_(5)SO_(4)]Br+Ag^(+)rarr AgBr(s)`
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