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The bond order in N(2) ^(-) is...

The bond order in `N_(2) ^(-)` is

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The electronic configurations should be written for the 4 molecule according to the buildup principle.
`{:(N_(2) ,, "(K electrons)" sigma_(s)^(2) sigma_(s)^(**2) pi_(x, y)^(4) sigma_(p_(z))^(2)) , (N_(2)^(+) ,, "(K electrons)" sigma_(s)^(2) sigma_(s)^(**2)pi _(x, y)^(4) sigma_(p_(z))^(1)), (NO ,, "(K electrons)" sigma_(s)^(2) sigma_(s)^(**2) pi_(x,y)^(4) sigma_(p_(z))^(2) pi_(x , y)^(** 1)), (NO^(+) ,, "(K electrons)" sigma_(s)^(2) sigma_(s)^(** 2) pi_(x , y)^(4) sigma_(p_(z))^(2)):}`
The computed bond orders for `N_2 and N_2^(+)` are 3 and `2 1/2`, respectively. `H_2` therfore has the stronger bond and should have the shorter bond length. The computed bond orders for NO and `NO^(+)` are `2 1/2` and 3, respectivley. `NO^(+)` has the stronger bond and should have the shorter bond length. As opposed to ionization of `N_2, which involves the loss of an electron in a bonding orbital, ionization of NO involves the loss of an electron in an antibonding orbital.
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NARAYNA-CHEMICAL BONDING AND MOLECULAR STRUCTURE-EXERCISE -4
  1. The bond order in N(2) ^(-) is

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  2. Among the following ions the p pi- d pi overlap could be present in

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  3. Nitrogen forms N(2) but phosphorous when forms P(2) gets readily conve...

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  4. The correct sequence of increasing covalent character is represented b...

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  5. Which of the following will no give a precipate with AgNO3?

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  6. AlCl3 anhydrous is covalent but AlCl3. 6H2O is ionic because

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  7. The correct stability order of the following resonance structures is ...

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  8. In PO(4)^(3-) ion the formal charge on the oxygen atom of P-O bond is

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  9. Arrange LiF, NaF, KF, RbF and CsF in order of increasing lattice energ...

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  10. Which of the following are arranged in the decreasing order of dipole ...

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  11. The dipole moment of is 1.5 D. The dipole moment of is:

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  12. The bond angle in H2S is

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  13. If H - X bond length is 2Å and H - X has dipole moment 5.12 xx 10^(-30...

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  14. Arrange the following compounds in order of increasing dipole moment ....

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  15. Which one of the following arrangements of molecules is correct on the...

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  16. Which of the following molecule has highest bond energy ?

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  17. In NO(3)^(-) ion, the number of bond pair and lone pair of electrons o...

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  18. Among the following the pair in which the two species are not isostruc...

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  19. In a regular octahedral molecule MX(6) the number of X - M - X bonds ...

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  20. In an octahedral structure , the pair of d orbitals involved in d^(2)...

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  21. In correct statement about the structure of PCl5

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