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The hybridisation of Nitrogen in Nitrate...

The hybridisation of Nitrogen in Nitrate ion is

A

sp

B

`sp^2`

C

`sp^3`

D

`sp^3d`

Text Solution

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The correct Answer is:
To determine the hybridization of nitrogen in the nitrate ion (NO3^-), we can follow these steps: ### Step 1: Identify the Lewis Structure of the Nitrate Ion - The nitrate ion consists of one nitrogen atom and three oxygen atoms. - In the Lewis structure, nitrogen is at the center, bonded to three oxygen atoms. One of these bonds is a double bond while the other two are single bonds. - The overall charge of the ion is -1, which is distributed among the oxygen atoms. ### Step 2: Count the Number of Sigma Bonds - In the nitrate ion, there are: - One double bond (N=O), which contributes one sigma bond and one pi bond. - Two single bonds (N-O), each contributing one sigma bond. - Therefore, the total number of sigma bonds is: - 1 (from the double bond) + 2 (from the single bonds) = 3 sigma bonds. ### Step 3: Determine the Hybridization - The number of hybrid orbitals formed corresponds to the number of sigma bonds. - Since there are 3 sigma bonds, nitrogen must have 3 hybrid orbitals. - The hybridization that corresponds to 3 hybrid orbitals is **sp²** hybridization (1 s orbital and 2 p orbitals mix to form 3 sp² hybrid orbitals). ### Step 4: Conclusion - Therefore, the hybridization of nitrogen in the nitrate ion (NO3^-) is **sp²**. ### Final Answer: The hybridization of nitrogen in the nitrate ion (NO3^-) is **sp²**. ---

To determine the hybridization of nitrogen in the nitrate ion (NO3^-), we can follow these steps: ### Step 1: Identify the Lewis Structure of the Nitrate Ion - The nitrate ion consists of one nitrogen atom and three oxygen atoms. - In the Lewis structure, nitrogen is at the center, bonded to three oxygen atoms. One of these bonds is a double bond while the other two are single bonds. - The overall charge of the ion is -1, which is distributed among the oxygen atoms. ### Step 2: Count the Number of Sigma Bonds ...
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Knowledge Check

  • The hybridisation of nitrogen in R_(2)NH is :

    A
    `sp^(3)`
    B
    `sp^(2)`
    C
    sp
    D
    `dsp^(2)`
  • The hybridisation of nitrogen in (pyrrole) is:

    A
    `sp^3`
    B
    `sp^2`
    C
    `sp`
    D
    Can't be predicted
  • Geometry of ammonia molcule and the hybridisation of nitrogen involved in it are

    A
    `sp^(3)`-hybridisation and tetrahedral geometry
    B
    `sp^(3)`-hybridisation and distorted tetrahedral geometry
    C
    `sp^(2)`- hybridisation and triangular geometry
    D
    None of the above
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