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Hybridisation in SO2 molecule is...

Hybridisation in `SO_2` molecule is

A

sp

B

`sp^2`

C

`sp^3`

D

`sp^3d`

Text Solution

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The correct Answer is:
To determine the hybridization of the sulfur dioxide (SO₂) molecule, we can follow these steps: ### Step 1: Determine the Valence Electrons - Sulfur (S) is in group 16 of the periodic table, which means it has 6 valence electrons. - Each oxygen (O) atom also has 6 valence electrons, and there are two oxygen atoms in SO₂. **Calculation:** - Total valence electrons = Valence electrons of S + 2 × Valence electrons of O - Total valence electrons = 6 + 2 × 6 = 6 + 12 = 18 electrons. **Hint:** Remember to count the valence electrons from both the central atom and the surrounding atoms. ### Step 2: Draw the Lewis Structure - In SO₂, sulfur forms double bonds with each oxygen atom. - Each double bond uses 4 electrons (2 from sulfur and 2 from oxygen). - After forming the two double bonds, sulfur will have 2 electrons left, which will remain as a lone pair. **Lewis Structure:** ``` O || S==O | Lone Pair ``` **Hint:** Drawing the Lewis structure helps visualize how atoms are bonded and how many lone pairs are present. ### Step 3: Count Bond Pairs and Lone Pairs - In the Lewis structure, there are 2 double bonds (which count as 2 bond pairs) and 1 lone pair on sulfur. - Therefore, we have: - Bond pairs = 2 - Lone pairs = 1 **Hint:** Count only the sigma bonds and lone pairs for determining hybridization. ### Step 4: Determine the Hybridization - The total number of regions of electron density (bond pairs + lone pairs) around the central atom (sulfur) is 3 (2 bond pairs + 1 lone pair). - According to VSEPR theory, if there are 3 regions of electron density, the hybridization is sp². **Hint:** Use the formula: Hybridization type = Number of regions of electron density. ### Step 5: Identify the Molecular Geometry - With sp² hybridization, the molecular geometry is trigonal planar. - This means the angles between the bonds are approximately 120 degrees. **Hint:** The geometry can help confirm the hybridization type based on the arrangement of electron pairs. ### Conclusion The hybridization of the sulfur atom in the SO₂ molecule is **sp²**. **Final Answer:** The hybridization in SO₂ is **sp²**. ---

To determine the hybridization of the sulfur dioxide (SO₂) molecule, we can follow these steps: ### Step 1: Determine the Valence Electrons - Sulfur (S) is in group 16 of the periodic table, which means it has 6 valence electrons. - Each oxygen (O) atom also has 6 valence electrons, and there are two oxygen atoms in SO₂. **Calculation:** - Total valence electrons = Valence electrons of S + 2 × Valence electrons of O ...
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