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At identical temperature and pressure th...

At identical temperature and pressure the rate of diffusion of hydrogen gas is `3sqrt3` times that of a hydrocarbon having molecular formula `C_(n)H_(2n-n)` What is the value of n ? .

A

1

B

4

C

3

D

8

Text Solution

Verified by Experts

The correct Answer is:
B

`(r_(H_(2)))/(r_(C_(n) H_(2n - 2))) = sqrt((M_(C_(n) H_(2n - 2)) = 3sqrt3 = sqrt(27)`
`implies M_(C_(n) H_(2n - 2)) = 27 xx 2 = 54`
Hence , `12 n + (2n - 2) xx 1 = 54`
`implies 14 n = 56 implies n = 4`
Thus , hydrocarbon is `C_(4) H_(6)` .
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