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The equilibrium constant for the reactio...

The equilibrium constant for the reaction is `H_(2)O_((l))+CO_((g)) Leftrightarrow H_(2(g))+CO_(2(g))` is 64. If the rate constant for the forward reaction is 160, the rate constant for the backward reaction is

A

0.4

B

2.5

C

6.2

D

`10.24 xx 10^(3)`

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The correct Answer is:
To solve the problem, we need to find the rate constant for the backward reaction given the equilibrium constant and the rate constant for the forward reaction. ### Step-by-Step Solution: 1. **Write down the equilibrium expression**: The equilibrium constant (K) for the reaction can be expressed in terms of the rate constants for the forward (kf) and backward (kb) reactions. The reaction is: \[ H_2O_{(l)} + CO_{(g)} \leftrightarrow H_2_{(g)} + CO_2_{(g)} \] 2. **Recall the relationship between K and rate constants**: The relationship is given by: \[ K = \frac{k_f}{k_b} \] where: - \( K \) is the equilibrium constant, - \( k_f \) is the rate constant for the forward reaction, - \( k_b \) is the rate constant for the backward reaction. 3. **Substitute the known values**: From the problem, we know: - \( K = 64 \) - \( k_f = 160 \) We can substitute these values into the equation: \[ 64 = \frac{160}{k_b} \] 4. **Rearrange the equation to solve for \( k_b \)**: To find \( k_b \), we can rearrange the equation: \[ k_b = \frac{160}{64} \] 5. **Calculate \( k_b \)**: Now, perform the division: \[ k_b = \frac{160}{64} = 2.5 \] 6. **Conclusion**: The rate constant for the backward reaction \( k_b \) is 2.5. ### Final Answer: The rate constant for the backward reaction is \( k_b = 2.5 \). ---
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