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The true statement about benzene is...

The true statement about benzene is

A

Because of unsaturation benzene easily undergoes addition reactions

B

There are two types `C-C` bonds in benzene molecule

C

There is a cyclilc delocalisationof pi - electrons in benzene

D

Mono substitutionof benzene gives three isomeric products

Text Solution

AI Generated Solution

The correct Answer is:
To determine the true statement about benzene, we will analyze the given statements one by one based on the properties and structure of benzene. ### Step-by-Step Solution: 1. **Understanding the Structure of Benzene:** - Benzene (C₆H₆) is a cyclic compound with a hexagonal ring structure. Each carbon atom in benzene is sp² hybridized, which means that each carbon forms three sigma bonds and has one unhybridized p-orbital that contributes to the delocalized π-electron cloud above and below the plane of the ring. 2. **Analyzing the First Statement:** - The first statement claims that benzene easily undergoes addition reactions due to unsaturation. - **Evaluation:** Benzene is stable due to resonance and aromaticity. It does not easily undergo addition reactions; instead, it prefers substitution reactions to maintain its aromatic character. Therefore, this statement is **false**. 3. **Analyzing the Second Statement:** - The second statement suggests that there are two types of C-C bonds in benzene. - **Evaluation:** In benzene, all C-C bond lengths are equal due to resonance. There is no distinction between single and double bonds; thus, there is only one type of C-C bond. This statement is **false**. 4. **Analyzing the Third Statement:** - The third statement states that there is a cyclic delocalization of π-electrons. - **Evaluation:** This is true. The π-electrons in benzene are delocalized over the entire ring structure, contributing to its stability and aromaticity. This statement is **true**. 5. **Analyzing the Fourth Statement:** - The fourth statement claims that monosubstitution of benzene gives three isomeric products. - **Evaluation:** When benzene undergoes monosubstitution, it typically yields only one type of product due to the equivalence of hydrogen atoms on the benzene ring. Therefore, this statement is **false**. ### Conclusion: The true statement about benzene is: **There is a cyclic delocalization of π-electrons.** ---

To determine the true statement about benzene, we will analyze the given statements one by one based on the properties and structure of benzene. ### Step-by-Step Solution: 1. **Understanding the Structure of Benzene:** - Benzene (C₆H₆) is a cyclic compound with a hexagonal ring structure. Each carbon atom in benzene is sp² hybridized, which means that each carbon forms three sigma bonds and has one unhybridized p-orbital that contributes to the delocalized π-electron cloud above and below the plane of the ring. 2. **Analyzing the First Statement:** ...
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