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(CH(3))(3)-C-MgCl on reaction with D(2)O...

`(CH_(3))_(3)-C-MgCl` on reaction with `D_(2)O` produces

A

`(CH_(3))_(3)CD`

B

`(CH_(3))_(3)COD`

C

`(CH_(3))_(3)CH`

D

`(CD_(3))_(3)COD`

Text Solution

Verified by Experts

The correct Answer is:
A

Grignard reagent on decomposition with water or other compounds having active hydrogen give alkane.
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(CH_(3))_(3)CMgBr on reaction with D_(2)O produces :

Me_3 C-MgCl on reaction with D_2 O produces :

(CH_3)_3CMgCl on reaction with D_2O produces

Identify the total number of following compounds which liberate CH_(4) gas on reaction with CH_(3)MgCl (i) H_(2)O (ii) CH_(2)=CH_(2) (iii) Me-C-=C-H

Which S_(N)1 reaction would you expect to take place more rapidly ? (a) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH+HCl Or (ii) (CH_(3))_(3)C Br+H_(2)O to (CH_(3))_(3)COH+HBr (b) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) C_(5)H_(5)Cl+H_(2)O to C_(5)H_(5)OH + HCl (c) (i) (CH_(3))_(3)C Cl+ H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) (CH_(3))_(3)C Cl+ CH_(3)OH to (CH_(3))_(3)COCH_(3)+ HCl (d) (i) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(1.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-) Or (ii) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(2.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-)

NARAYNA-HYDROCARBONS -EXERCISE - 2 (H.W)
  1. Which of the following reactions has Zero activation energy?

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  2. Which of the following can produce a racemic mixture on monobrominatio...

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  3. underset("(A) (B)"){:(" ...

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  4. Xoverset(NaOH+CaO)toCH(3)-underset(CH(3))underset(|)overset(CH(3))over...

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  5. CH(2)=CH(2)+H(2)overset(Pt, T(1)K)rarrC(2)H(6) CH(2)=CH(2)+H(2)overs...

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  6. 2-Methylbutane on reacting with bromine in the presence of sunlight gi...

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  7. Which of the following is not obtained when propyl chloride and methyl...

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  8. The volume of methane at N.T.P formed from 8.2 g of sodium acetate by ...

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  9. Reaction of ROH with R'MgX produces

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  10. In Wurtz reaction, n-hexane is obtained from

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  11. The increasing order of reduction of alkyl halides with zinc and dilut...

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  12. nitroethane ca be obtained from ethane by following

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  13. The following substance reacts with ater to give ethane

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  14. (CH(3))(3)-C-MgCl on reaction with D(2)O produces

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  15. The ratio of products, 1 - chloropropane to 2 - chloropropane respecti...

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  16. Of the five isomeric hexanes, the isomer which can give two monochlori...

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  17. Alkyl halides react with dialkyl copper reagents to give

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  18. 2.84 g of methayl iodide was completely converted into methyl magnesiu...

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  19. Which liberate methane gas on treatment with water?

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  20. As compared to melting poitns of even carbon chaini isomers,t he melti...

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