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For the reaction A + B to products, it ...

For the reaction `A + B to` products, it is found that order of A is 1 and order of B is 1/2. When concentrations of both A & B are increased four times the rate will increase by a factor

A

6

B

8

C

4

D

16

Text Solution

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The correct Answer is:
To solve the problem, we need to determine how the rate of the reaction changes when the concentrations of reactants A and B are increased four times. We know the order of the reaction with respect to A and B, which are given as follows: - Order of A = 1 - Order of B = 1/2 ### Step-by-Step Solution: 1. **Write the Rate Law Expression**: The rate law for the reaction can be expressed as: \[ \text{Rate} (R) = k [A]^m [B]^n \] where \( k \) is the rate constant, \( m \) is the order with respect to A, and \( n \) is the order with respect to B. Given the orders: \[ R = k [A]^1 [B]^{1/2} = k [A] [B]^{1/2} \] 2. **Determine the Initial Rate**: Let the initial concentrations of A and B be \( [A] \) and \( [B] \) respectively. The initial rate can be expressed as: \[ R_0 = k [A] [B]^{1/2} \] 3. **Increase Concentrations**: When the concentrations of both A and B are increased four times, the new concentrations will be: \[ [A]' = 4[A] \] \[ [B]' = 4[B] \] 4. **Calculate the New Rate**: Substitute the new concentrations into the rate law to find the new rate \( R' \): \[ R' = k [A]' [B]'^{1/2} = k (4[A]) (4[B])^{1/2} \] Simplifying this, we have: \[ R' = k (4[A]) (2\sqrt{4[B]}) = k (4[A]) (2[B]^{1/2}) = k \cdot 8 [A] [B]^{1/2} \] 5. **Compare the New Rate with the Initial Rate**: Now we can compare the new rate \( R' \) with the initial rate \( R_0 \): \[ R' = 8 \cdot k [A] [B]^{1/2} = 8 R_0 \] 6. **Conclusion**: Therefore, the rate increases by a factor of 8 when the concentrations of A and B are increased four times. ### Final Answer: The rate will increase by a factor of **8**.

To solve the problem, we need to determine how the rate of the reaction changes when the concentrations of reactants A and B are increased four times. We know the order of the reaction with respect to A and B, which are given as follows: - Order of A = 1 - Order of B = 1/2 ### Step-by-Step Solution: 1. **Write the Rate Law Expression**: ...
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