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A + B to products is an elementary react...

`A + B to` products is an elementary reaction. When excess of A is taken in this reaction,then the molecularity and order are respectively

A

2 and 2

B

2 and 1

C

1 and 2

D

1 and 1

Text Solution

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The correct Answer is:
To solve the question regarding the molecularity and order of the reaction \( A + B \to \text{products} \) when excess of \( A \) is taken, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction Type**: - The reaction \( A + B \to \text{products} \) is stated to be an elementary reaction. This means it occurs in a single step and the stoichiometry directly reflects the molecularity. 2. **Determine Molecularity**: - Molecularity is defined as the number of reactant molecules involved in an elementary reaction. In this case, we have one molecule of \( A \) and one molecule of \( B \) reacting together. - Therefore, the molecularity of the reaction is \( 1 + 1 = 2 \). 3. **Write the Rate Law Expression**: - The rate law for an elementary reaction can be written as: \[ \text{Rate} = k[A]^1[B]^1 \] - When \( A \) is in excess, the concentration of \( A \) does not change significantly during the reaction, and thus we can consider it constant. 4. **Adjust the Rate Law for Excess \( A \)**: - When \( A \) is in excess, we can express the rate law as: \[ \text{Rate} = k'[B]^1 \] - Here, \( k' = k[A] \) (where \( [A] \) is treated as a constant). 5. **Determine the Order of the Reaction**: - The order of a reaction is defined as the sum of the powers of the concentration terms in the rate law expression. In this case, since we have only \( B \) in the rate law after considering \( A \) in excess, the order is: \[ \text{Order} = 1 \] 6. **Final Answer**: - Thus, the molecularity of the reaction is \( 2 \) and the order of the reaction is \( 1 \). ### Summary: - **Molecularity**: 2 - **Order**: 1

To solve the question regarding the molecularity and order of the reaction \( A + B \to \text{products} \) when excess of \( A \) is taken, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction Type**: - The reaction \( A + B \to \text{products} \) is stated to be an elementary reaction. This means it occurs in a single step and the stoichiometry directly reflects the molecularity. 2. **Determine Molecularity**: ...
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