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Among the trihalides of nitrogen, which ...

Among the trihalides of nitrogen, which is the least basic ?

A

`NF_(3)`

B

`NCl_(3)`

C

`NBr_(3)`

D

`NI_(3)`

Text Solution

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The correct Answer is:
A
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The pronounced change from non-metallic behaviour and also increase in the basicity of oxides from nitrogen to bismuth in group 15 is principally due to incresing size of the atoms. The ionisation potential of nitrogen is very high on account of its small size. However, ionisation potential decreases regularly on descending the group. Among the trihalides of nitrogen, which one is least basic ?

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NARAYNA-15TH GROUP ELEMENTS-EXERCISE - 3 (PREVIOUS QUESTIONS)
  1. Thermal decomposition of zinc nitrate give:

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  2. The total number of sigma and pi-bonds in pyrophosphoric acid are resp...

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  3. Chloroethane reacts with Y to form NaCl and Z. One mole of Z reacts wi...

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  4. Three reactions involving H(2)PO(4)^(-) are given below I. H(3)PO(4...

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  5. Which one of the oxides of nitrogen dimerises into colourless solid/li...

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  6. Which one of the acids is a dibasic acid ?

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  7. Among the trihalides of nitrogen, which is the least basic ?

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  8. Which one of the following pairs is obtained on heating ammonium dichr...

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  9. The hybridization of atomic orbitals of nitrogen is NO(2)^(+), NO(3)^(...

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  10. A metal X on heating in nitrogen gas gives Y,Y on treatment with H(2)O...

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  11. Very pure nitrogen can be obtained by :

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  12. The reaction of white phosphorus with aqueous NaOH gives phosphine alo...

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  13. The molecule having smallest bond angle is

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  14. Which of the following oxides of nitrogen is the anhydride of nitrous ...

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  15. The hydrolsis of NCl(3) by water produces

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  16. For H(3)PO(3) and H(3)PO(4) the correct choice is :

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  17. In which of the following compounds, nitrogen exhibits highest oxidati...

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  18. Which of the following statement is not valid for oxoaids of phosphoru...

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  19. Strong reducing behaviour of H(3)PO(2) is due to

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  20. Nitrogen dioxide and sulphur dioxide have some properties in common, w...

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