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In the preparation of alkyl halide from ...

In the preparation of alkyl halide from alkene and halogen which of the following reaction is involved

A

Free radical substitution

B

Nuclephilic addition

C

Electrophilie substitution

D

Nucleophilic substitution

Text Solution

AI Generated Solution

The correct Answer is:
### Step-by-Step Solution: 1. **Identify the Reactants**: - We start with an alkene, for example, propene (C3H6), which has the structure CH2=CH-CH3. - We will react this alkene with a halogen, such as chlorine (Cl2). 2. **Reaction Setup**: - The reaction involves treating propene with chlorine gas (Cl2) in the presence of heat. The reaction can be represented as: \[ \text{CH}_2=\text{CH-CH}_3 + \text{Cl}_2 \xrightarrow{\text{heat}} \text{3-chloropropene} \] 3. **Mechanism of the Reaction**: - The reaction proceeds through a free radical mechanism. - The Cl2 molecule undergoes homolytic cleavage upon heating, generating two chlorine radicals (Cl•): \[ \text{Cl}_2 \xrightarrow{\text{heat}} 2 \text{Cl}• \] 4. **Radical Attack**: - One of the chlorine radicals attacks the propene. The chlorine radical will preferentially abstract a hydrogen atom from the propene, leading to the formation of a radical on the carbon: \[ \text{CH}_2=\text{CH-CH}_3 + \text{Cl}• \rightarrow \text{CH}_2•-\text{CH-CH}_3 + \text{HCl} \] - This results in the formation of a CH2 radical and HCl. 5. **Formation of Alkyl Halide**: - The generated CH2 radical can now react with another chlorine molecule (Cl2). The chlorine radical will again undergo homolytic cleavage: \[ \text{CH}_2• + \text{Cl}_2 \rightarrow \text{CH}_2\text{Cl}-\text{CH-CH}_3 \] - This results in the formation of 3-chloropropene, which is the alkyl halide. 6. **Conclusion**: - The overall reaction is a free radical substitution reaction, where a chlorine radical substitutes a hydrogen atom in the alkene to form an alkyl halide. ### Final Answer: The reaction involved in the preparation of alkyl halide from alkene and halogen is **free radical substitution**. ---
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