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CH3OHoverset(PI3)rarr(A)overset(KCN)rarr...

`CH_3OHoverset(PI_3)rarr(A)overset(KCN)rarr(B)overset("Hydrolysis")rarr(C).`
The compound (C) is :

A

`CH_3OH`

B

`HCOOH`

C

`CH_3CHO`

D

`CH_3COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reactions sequentially. ### Step 1: Formation of Compound A - We start with **methanol (CH₃OH)** and react it with **phosphorus triiodide (PI₃)**. - The reaction of an alcohol with PI₃ converts the alcohol into the corresponding alkyl iodide. - Therefore, when methanol reacts with PI₃, we get **methyl iodide (CH₃I)**. **Compound A:** CH₃I ### Step 2: Formation of Compound B - Next, we take **methyl iodide (CH₃I)** and react it with **potassium cyanide (KCN)**. - KCN dissociates into K⁺ and CN⁻ ions in solution. The CN⁻ ion acts as a nucleophile. - In an SN2 reaction, the nucleophile (CN⁻) attacks the electrophilic carbon in methyl iodide, displacing the iodide ion (I⁻), which is a good leaving group. - This results in the formation of **methyl cyanide (CH₃CN)**. **Compound B:** CH₃CN ### Step 3: Formation of Compound C - Finally, we take **methyl cyanide (CH₃CN)** and subject it to **hydrolysis**. - Hydrolysis of nitriles (like methyl cyanide) involves the addition of water, which converts the nitrile into the corresponding carboxylic acid. - Therefore, hydrolysis of CH₃CN yields **acetic acid (CH₃COOH)**. **Compound C:** CH₃COOH ### Final Answer The compound (C) is **acetic acid (CH₃COOH)**. ---

To solve the problem step by step, we will analyze the reactions sequentially. ### Step 1: Formation of Compound A - We start with **methanol (CH₃OH)** and react it with **phosphorus triiodide (PI₃)**. - The reaction of an alcohol with PI₃ converts the alcohol into the corresponding alkyl iodide. - Therefore, when methanol reacts with PI₃, we get **methyl iodide (CH₃I)**. **Compound A:** CH₃I ...
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NARAYNA-HALOALKANE AND HALOARENES-EXERCISE - I (C.W)
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