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Which of the following pairs of d-electr...

Which of the following pairs of d-electron configuration exhibit both low and high spin tetrahedral complex

A

`d^(1), d^(2)`

B

`d^(3), d^(4)`

C

`d^(7),d^(8)`

D

`d^(9),d^(10)`

Text Solution

Verified by Experts

The correct Answer is:
B

`d^(3) and d^(4)` systems have `e^(2)t_(2g)^(1) and e^(2)t_(2g)^(2)` (high spin state) configuration. In weak field are `e^(3)t_(2g)^(0) and e^(4)t_(2g)^(0)` (low spin state) configurations.
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NARAYNA-CO-ORDINATE COMPOUNDS -Exercise-4
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  2. Which of the following are paramagnetic?

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  3. Which of the following pairs of d-electron configuration exhibit both ...

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  4. Assign the hybridisation, shape and magnetic moment of K(2)[Cu(CN)(4)]

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  5. Which of the following is most stable.

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  6. Valence bond theory successfully explains the magnetic behaviour of co...

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  7. There are four complexes of Ni. Select the complexes/es which will be ...

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  8. The magnetic moment of complex given below are in the order: (I) [Ni...

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  9. The magnetic moments of [Cu(NH(3))(4)]^(2+) was found to be 1.73 B.M. ...

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  10. When two or more simple salts are mixed in stoichiometric proportions ...

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  11. Mohr's salt on dissociation in water gives

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  12. Complex compound is made up of

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  13. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  14. The reducing power of the metal decreases in the order:

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  15. Which of these species has same number of unpaired electrons with weak...

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  16. Why are low spin tetrahedral complexes not formed ?

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  17. Value of CFSE, in tetrahedral complex having 3d^4 configuration of met...

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  18. The non -existant metal carbonyl among the following is

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  19. The pi - bounded organometallic compound which has ethylene as one of ...

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  20. If X' is a Anti cancerous drug which of the following conversions will...

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