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Given that maximum absorption for d-d tr...

Given that maximum absorption for d-d transition in `[Ti(H_2O)_(6)]^(3+)` occurs at 20300 `cm^(-1)` predict where the peak (d-d transition) will occur for `[Ti(CN)_6]^(3-) and [Ti(CI)_6]^(3-)` respectively:

A

`2300 cm^(-1), 32000 cm^(-1)`

B

`18000 cm^(-1), 21300 cm^(-1)`

C

`23000 cm^(-1), 17300cm^(-1)`

D

`18000cm^(-1), 17300 cm^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A

Since field strength of ligands `Cl lt H_(2)O lt CN^(-)`
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