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The product of the chemical reaction, ...

The product of the chemical reaction,
`CH_(3)-overset(O)overset(||)C-NH_(2)+Br+4NaOH to` will be

A

`CH_(4)`

B

`CH_(3)Br`

C

`CH_(3)OBr`

D

`CH_(3)NH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given chemical reaction, we will follow the steps outlined in the video transcript. The reaction involves the amide CH₃CONH₂ (acetamide) reacting with bromine (Br₂) and sodium hydroxide (NaOH). ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are: - CH₃CONH₂ (acetamide) - Br₂ (bromine) - 4 NaOH (sodium hydroxide) 2. **Understand the Role of NaOH**: NaOH acts as a base in this reaction. It will abstract a proton (H⁺) from the amide group (NH₂) of acetamide. 3. **Deprotonation**: The base (OH⁻ from NaOH) abstracts a proton from the nitrogen of acetamide, forming the anion CH₃CONH⁻. 4. **Nucleophilic Attack**: The negatively charged nitrogen (from CH₃CONH⁻) attacks one of the bromine atoms in Br₂, resulting in the formation of CH₃CONHBr (bromacetamide). 5. **Formation of Imine**: The base (OH⁻) again abstracts a proton from the nitrogen, leading to the formation of a double bond between carbon and nitrogen, yielding CH₃C=NH (an imine). 6. **Hydrolysis**: The imine undergoes hydrolysis in the presence of water, resulting in the formation of CH₃NH₂ (methylamine) and carbon dioxide (CO₂). 7. **Side Products**: The side products of the reaction include: - 2 moles of NaBr (sodium bromide) - Na₂CO₃ (sodium carbonate) - Water (H₂O) 8. **Final Product**: The main product of the reaction is CH₃NH₂ (methylamine). ### Summary of the Reaction: The overall reaction can be summarized as: \[ \text{CH}_3\text{CONH}_2 + \text{Br}_2 + 4 \text{NaOH} \rightarrow \text{CH}_3\text{NH}_2 + 2 \text{NaBr} + \text{Na}_2\text{CO}_3 + 2 \text{H}_2\text{O} \] ### Final Answer: The product of the chemical reaction is CH₃NH₂ (methylamine). ---
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NARAYNA-ORGANIC COMPOUNDS CONTAINING NITROGEN-CUQ (IUPAC NAMING OF AMINES)
  1. The total number of structural isomers possible for an amine with mole...

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  2. Which one of the following is not a primary amine ?

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  3. Which of the following is a secondary amine ?

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  4. Carbylamine reaction is given by

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  5. How many primary amines are possible for the formula C4 H(11) N

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  6. Which of the following should be most valatile ? CH(3)CH(2)CH(2)NH(2...

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  7. The structure given below represents CH(3)-underset(CH(3))underset(|...

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  8. The product of the chemical reaction, CH(3)-overset(O)overset(||)C-N...

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  9. Gabriel phthalimide synthesis is used in the preparation of

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  10. Which of the following reactions does not yield an amine ?

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  11. In the given set of reactions : 2-"Bromopropane " overset("alc.AgCN"...

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  12. The major product formed when alkyl iodides is treated with excess of ...

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  13. Which one of the following reagent will convert acetamide to ethanamin...

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  14. Aniline is more basic than

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  15. Which of the following is the strongest base ?

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  16. In the reaction of C(6)H(5)OH overset(NH(2))underset(ZnCl(2))toX, 'X' ...

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  17. During the nitration of aniline, the amino group is protected by

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  18. Aniline when treated with benzoyl chloride, gives benzanilide the reac...

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  19. In phenyl isocyanide the carbons are hybridised.

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  20. Schiffs base is used as a

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