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The product of the chemical reaction, ...

The product of the chemical reaction,
`CH_(3)-overset(O)overset(||)C-NH_(2)+Br_(2)+4NaOH to` ? Will be

A

`CH_(4)`

B

`CH_(3)NBr`

C

`CH_(3)Obr`

D

`CH_(3)NH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction step by step. The reaction given is: \[ \text{CH}_3\text{C(=O)NH}_2 + \text{Br}_2 + 4\text{NaOH} \] ### Step 1: Identify the Reactants The reactants are: - Acetamide (\( \text{CH}_3\text{C(=O)NH}_2 \)) - Bromine (\( \text{Br}_2 \)) - Sodium Hydroxide (\( \text{NaOH} \)) ### Step 2: Mechanism of Reaction 1. **Deprotonation**: The hydroxide ion (\( \text{OH}^- \)) from sodium hydroxide acts as a base and abstracts a proton from the amide group of acetamide. This generates a negatively charged nitrogen species. \[ \text{CH}_3\text{C(=O)NH}_2 + \text{OH}^- \rightarrow \text{CH}_3\text{C(=O)N}^- + \text{H}_2\text{O} \] 2. **Bromination**: The negatively charged nitrogen then attacks one of the bromine atoms in \( \text{Br}_2 \), leading to the formation of a brominated intermediate. \[ \text{CH}_3\text{C(=O)N}^- + \text{Br}_2 \rightarrow \text{CH}_3\text{C(=O)NBr} + \text{Br}^- \] 3. **Further Deprotonation**: The base (sodium hydroxide) abstracts another proton from the nitrogen, resulting in a more stable intermediate. \[ \text{CH}_3\text{C(=O)NBr} + \text{OH}^- \rightarrow \text{CH}_3\text{C(=O)N}^- + \text{Br}^- + \text{H}_2\text{O} \] 4. **Formation of Product**: The negatively charged nitrogen can now undergo a rearrangement where a methyl group from the carbon chain migrates to the nitrogen, forming a double bond between carbon and nitrogen. \[ \text{CH}_3\text{C(=O)N}^- \rightarrow \text{CH}_3\text{N}H + \text{CO}_2 \] ### Step 3: Final Products The final products of the reaction are: - Methylamine (\( \text{CH}_3\text{NH}_2 \)) - Sodium bromide (\( \text{NaBr} \)) - Water (\( \text{H}_2\text{O} \)) - Carbon dioxide (\( \text{CO}_2 \)) ### Step 4: Summary of the Reaction The overall reaction can be summarized as: \[ \text{CH}_3\text{C(=O)NH}_2 + \text{Br}_2 + 4\text{NaOH} \rightarrow \text{CH}_3\text{NH}_2 + 2\text{NaBr} + \text{Na}_2\text{CO}_3 + 2\text{H}_2\text{O} \] ### Final Answer The main product of the reaction is **Methylamine (\( \text{CH}_3\text{NH}_2 \))**. ---

To solve the problem, we need to analyze the reaction step by step. The reaction given is: \[ \text{CH}_3\text{C(=O)NH}_2 + \text{Br}_2 + 4\text{NaOH} \] ### Step 1: Identify the Reactants The reactants are: - Acetamide (\( \text{CH}_3\text{C(=O)NH}_2 \)) - Bromine (\( \text{Br}_2 \)) ...
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