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Identify the product C in the series. ...

Identify the product C in the series.
`C_(6)H_(5)NO_(2) overset(FeHCl) to A underset(273 K)overset(NaNO_(2)+HCl) to B underset(283)overset(H_(2)O)to C`

A

`C_(6)H_(5)OH`

B

`C_(6)H_(5)CH_(2)OH`

C

`C_(6)H_(5)CHO`

D

`C_(6)H_(5)NH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To identify the product C in the given series, we will follow the steps outlined in the question: ### Step 1: Identify the starting compound The starting compound is C₆H₅NO₂, which is nitrobenzene. ### Step 2: Reduction of nitrobenzene The first reaction involves the reduction of nitrobenzene (C₆H₅NO₂) using Fe in the presence of HCl. This reaction reduces the nitro group (-NO₂) to an amino group (-NH₂), resulting in the formation of aniline (C₆H₅NH₂). **Reaction:** C₆H₅NO₂ + Fe + HCl → C₆H₅NH₂ (Aniline) ### Step 3: Diazotization of aniline The next step involves the diazotization of aniline (C₆H₅NH₂) using sodium nitrite (NaNO₂) and hydrochloric acid (HCl) at 273 K. This reaction converts the amino group (-NH₂) into a diazonium group (-N₂⁺), resulting in the formation of benzene diazonium chloride (C₆H₅N₂Cl). **Reaction:** C₆H₅NH₂ + NaNO₂ + HCl → C₆H₅N₂Cl (Benzene diazonium chloride) ### Step 4: Hydrolysis of benzene diazonium chloride The final step involves the hydrolysis of benzene diazonium chloride (C₆H₅N₂Cl) in the presence of water (H₂O) at 283 K. This reaction replaces the diazonium group (-N₂⁺) with a hydroxyl group (-OH), resulting in the formation of phenol (C₆H₅OH). **Reaction:** C₆H₅N₂Cl + H₂O → C₆H₅OH (Phenol) + N₂ (gas) ### Conclusion The product C in the series is phenol (C₆H₅OH). ### Summary of Products: - A: Aniline (C₆H₅NH₂) - B: Benzene diazonium chloride (C₆H₅N₂Cl) - C: Phenol (C₆H₅OH) ### Final Answer: The product C is **C₆H₅OH (Phenol)**. ---

To identify the product C in the given series, we will follow the steps outlined in the question: ### Step 1: Identify the starting compound The starting compound is C₆H₅NO₂, which is nitrobenzene. ### Step 2: Reduction of nitrobenzene The first reaction involves the reduction of nitrobenzene (C₆H₅NO₂) using Fe in the presence of HCl. This reaction reduces the nitro group (-NO₂) to an amino group (-NH₂), resulting in the formation of aniline (C₆H₅NH₂). ...
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