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Acetamide is treated with the following ...

Acetamide is treated with the following reagents seprately.Which one of these would yield methyl amine?

A

`PCl_(5)`

B

`NaOH-Br_(2)`

C

Sodalime

D

Hot conc. `H_(2)SO_(4)`

Text Solution

Verified by Experts

The given reaction is the example of Hofmann-bromamide reaction.
`underset("acetamide")(CH_(3)CONH_(2)) overset(NaOH+Br_(2)) to underset("methyl amine")(CH_(3)NH_(2))`
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NARAYNA-ORGANIC COMPOUNDS CONTAINING NITROGEN-EXERCISE-3
  1. Which of the following reaction can produce aniline as main product ?

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  2. Which of the following statements about primary amines is false ? .

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  3. Acetamide is treated with the following reagents seprately.Which one o...

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  4. Primary, secondary and tertiary amines can be distinguished by

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  5. N(2) gas will not be evolved upon reaction of HNO(2) with which of the...

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  6. An organic compound A(C(3)H(9)N) when treated with ntrous acid gave an...

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  7. Nitrobenzene on reaction with conc HNO(3)//H(2)SO(4) at 80-100^(@)C fo...

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  8. In the reaction A is

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  9. Which of the following compounds will not undergo Friedel- Crafts reac...

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  10. Which of the following reagents would not be a good choice for reducin...

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  11. Which of the following will be most stable diazonium salt RN2^(+)X^(-)...

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  12. In the following reaction, the product (A) is

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  13. The number of structure isomers possible from the molecular formula C(...

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  14. The following reaction is known by the name :

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  15. Method by which aniline cannot be prepared is:

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  16. The electrolytic reduction of nitrobenzene in strongly acidic medium p...

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  17. Which of the following reagents cannot be used for the given conversio...

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  18. Which one of the following isomeric amines has the highest boiling poi...

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  19. Which amine amongst the following will answer positively the carbylami...

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  20. An organic compound 'A' on reduction give compound 'B' which on reacti...

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