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Calculate the standard entropy of formation `DeltaS_(f)^(@) " of "CO_(2_((g)))` . Given the standard entropies of `CO_(2_((g))),C_((s)),O_(2_((g)))` as `218.8,8.740and 205.60Jk^(-1)` respectively .

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Standard entropy of formation is defined as "the entropy of formation of 1 mole of a compound from the elements under standard conditions. It is denoted as `DeltaS_f^0`
We can calculate the value of entropy of a given compound from the values of `S^0` of elements
`DeltaS_f^0=sum DeltaS_"products"^0 - sum DeltaS_"reactants"^0`
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C_((s))+O_(2(g)) to CO_(2(g)) Calculate the standard entropy change for the above reaction, given the standard entropies of CO_(2(g)), C_((S)), O_(2(g)) are 213.6, 5.740 and 205 JK^(-1) respectively.

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The standard entropy change Delta S_r^@ for CH_(4(g)) + 2O_(2(g)) to CO_(2(g)) + 2H_2O_((l)) is -242.98 JK^(-1) at 25^@C . Calculate the standard reaction enthalpy for the above reaction if standard Gibbs energy of formation of CH_(4(g)), CO_(2(g)) and H_2O_((l)) are -50.72, -394.36 and - 237.13 kJ mol^(-1) respectively.

In the reaction 1/2N_(2(g)) + 3/2 H_(2(g)) to NH_(3(g)) . The standard entropies of N_(2(g)), H_(2(g)) and NH_(3(g)) are 191.6,130.5 and 192.5 JK^(-1) "mol"^(-1) respectivly. If free energy charge of the reaction is -16.67 kJ. Calculate the Delta H_("reaction")^@ for the formation of NH_3 at 298 K.

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FULL MARKS-THERMODYNAMICS -Additional Questions Solved (II) Answer briefly
  1. Define molar heat of fusion.

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  2. What is meant by molar heat of vaporization?

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  3. (i) What is sublimation? (ii) Define molar heat of sublimation.

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  4. Define heat of transition?

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  5. How do you measure the enthalpy of formation of carbon monoxide?

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  6. What are the Important features of lattice enthalpy?

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  7. Why there is need for second law of thermodynamics? Give its importanc...

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  8. Write the entropy statement of second law of thermodynamics.

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  9. State Clausius form of the second law of thermodynamics.

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  10. What are spontaneous reaction? Give three examples for spontaneous rea...

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  11. Calculate the standard entropy of formation DeltaS(f)^(@) " of "CO(2((...

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  12. What is entropy of fusion?

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  13. What is entropy of Vaporization?

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  14. Define entropy of transition.

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  15. Explain the following: (i)Out of diamond and graphite, which has gre...

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  16. What is the condition spontaneity in terms of free energy change?

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  17. Why standard entropy of an elementary substance is not zero whereas st...

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  18. The equilibrium constant for a reaction is one or more if DeltaG^Ө for...

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  19. Many thermodynamically feasible reactions do not occur under ordinary ...

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  20. Predict in which of the following , entropy increases or decreases . ...

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