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A chemist prepares 1.00 g of pure .(6)C^...

A chemist prepares `1.00 g` of pure `._(6)C^(11)`. This isotopes has half life of 21 min, decaying by the equation: `._(6)C^(11)`.`=>` `._(5)B^(11)`. + `._(-1)e^(0)`.
a. What is the rate of disintegration per second (dps) at starts ?
b. What is the activity and specific activity of `._(6)C^(11)` at start?
c. How much of this isotope `(._(6)C^(11))` is left after 24 hr its preparation?

Text Solution

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Applying, `-(dN)/(dt) = lambda N_(0)`
`= (0.693)/(21 xx 60) xx (1 xx 6.02 xx 10^(23))/(11)`
`= 3 xx 10^(19)` dps
(b) Activity `= (3 xx 10^(19))/(3.7 xx 10^(10))` (1 curie `= 3.7 xx 10^(10)` dps)
`= 8.108 xx 10^(8)` curie
Sp. activity ` = 3 xx 10^(19) xx 10^(3) = 3 xx 10^(22)` dis/kg s
= `8.108 xx 10^(11)` curie
(c ) Applying, `N = N_(0) ((1)/(2))^(n) [n = (t)/(t_(1//2)) = (24 xx 60)/(21) = 68.57]`
`N = 1 xx ((1)/(2))^(68.57) = 2.29 xx 10^(-21) g`
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