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Carbocation as an intermediate is likely...

Carbocation as an intermediate is likely to be formed in the reaction :

A

Propene`+Cl_(2) overset(hv) rarr`2- chloropropane

B

Acetone `+HCN overset(""^(-)OH)rarr` acetonecyanohydrin

C

Ethyl bromide `+ Aq. KOH overset(Delta) rarr` ethyl alcohol

D

Hexane `overset("Anhy."AlCl_(3)//HCl)rarr` 2-methylpentane

Text Solution

Verified by Experts

The correct Answer is:
D

`CH_(3)CH_(2)CH_(2)CH_(2)CH_(2)CH_(3) underset("Isomerisation")overset("Anhy."AlCl_(3)//HCl)rarr underset("2-Methylpentane")overset(" "CH_(3))overset(" |")(CH_(3)CH_(2)CH_(2)CHCH_(3))`
This involves the formation of carbocation as an intermediate.
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