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Dichloroacetic acid (CHCI2COOH) is oxidi...

Dichloroacetic acid `(CHCI_2COOH)` is oxidised to `CO_(2),H_(2)O` and `CI_(2)` by 600meq of an oxidising agent. Same amount of ammonia to form ammonium dichloroacetate:

A

0.0167

B

0.1

C

0.3

D

0.6

Text Solution

Verified by Experts

The correct Answer is:
B

`eq_(acid)=eq_(base)` (VF=1for both)
`CHCl_(2)CO OH+NH_(3)rarrCHCl_(2)CO ONH_(4)`
From reaction, m.moles of `NH_(3)`=m.moles of dichloroacetic acid = 100
`:. ` Moles of `NH_(3)=(100)/(1000)=0.1`
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